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The effect of strain rate on solvent crazing of poly(ethylene terephthalate) in solutions of poly(ethylene oxide) of various molecular masses

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Abstract

The effect of strain rate on the behavior of PET during its tensile drawing in highly viscous liquids, such as liquid PEG (M 400) and semidilute solutions of PEO (M = (4 × 104)−(1 × 106)), is studied. With an increase in strain rate, the mechanism of tensile drawing of PET in PEG changes from solvent crazing to shearing; at the same time, over the selected interval of strain rates, tensile drawing of PET in semidilute solutions of PEO proceeds via the mechanism of solvent crazing. During tensile drawing of PET in PEO solutions, the behavior of PET is almost the same as the mechanism of tensile drawing in a pure solvent. This result indicates that, in the course of flow of the polymer solution through the formed porous structure, PEO is filtered off in the local tip region of the growing craze.

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References

  1. R. P. Kambour, J. Macromol. Sci., Rev. Macromol. Chem. 7, 1 (1973).

    Google Scholar 

  2. E. J. Kramer, Adv. Polym. Sci. 52–53, 2 (1983).

    Google Scholar 

  3. E. J. Kramer and L. Berger, Adv. Polym. Sci. 91–92, 1 (1990).

    Article  Google Scholar 

  4. L. M. Yarysheva, G. M. Lukovkin, A. L. Volynskii, and N. F. Bakeev, Features of Rehbinder Effect in Polymers (Nauka, Moscow, 1992) [in Russian].

    Google Scholar 

  5. A. L. Volynskii and N. F. Bakeev, Solvent Crazing of Polymers (Elsevier, Amsterdam, 1995).

    Google Scholar 

  6. A. L. Volynskii, Priroda (Moscow, Russ. Fed.), No. 11, 11 (2006).

    Google Scholar 

  7. A. L. Volynskii and N. F. Bakeev, Structural Self-Organization of Amorphous Polymers (Fizmatlit, Moscow, 2005) [in Russian].

    Google Scholar 

  8. R. Estevez, M. G. A. Tijssens, and E. Van der Giessen, J. Mech. Phys. Solids 48, 2585 (2000).

    Article  CAS  Google Scholar 

  9. A. L. Volynskii and N. F. Bakeev, Highly Dispersed Oriented State of Polymers (Khimiya, Moscow, 1985) [in Russian].

    Google Scholar 

  10. A. L. Volynskii, N. A. Shitov, and N. F. Bakeev, Vysokomol. Soedin., Ser. A 23, 859 (1981).

    CAS  Google Scholar 

  11. A. L. Volynskii, N. A. Shitov, and N. F. Bakeev, Vysokomol. Soedin., Ser. A 23, 978 (1981).

    CAS  Google Scholar 

  12. N. A. Shitov, Candidate’s Dissertation in Chemistry (Moscow, 1983).

  13. E. G. Rukhlya, O. V. Arzhakova, L. M. Yarysheva, et al., Polymer Science, Ser. B 49 (2007) [Vysokomol. Soedin., Ser. B 49, 920 (2007)].

    Google Scholar 

  14. E. G. Rukhlya, O. V. Arzhakova, A. A. Dolgova, et al., Int. J. Polym. Anal. Charact. 12, 65 (2007).

    Article  Google Scholar 

  15. E. G. Rukhlya, L. M. Yarysheva, A. L. Volynskii, and N. F. Bakeev, Polymer Science, Ser. B 49 (2007) [Vysokomol. Soedin., Ser. B 49 1876 (2007)].

    Google Scholar 

  16. A. L. Volynskii, E. G. Rukhlya, L. M. Yarysheva, and N. F. Bakeev, Ross. Nanotekhnol. 2(5–6), 44 (2007).

    Google Scholar 

  17. G. M. Lukovkin, Doctoral Dissertation in Chemistry (Moscow, 1986).

  18. A. L. Volynskii, L. M. Yarysheva, and N. F. Bakeev, Polymer Science, Ser. C 43 (2001) [Vysokomol. Soedin., Ser. C 43, 2289 (2001)].

    Google Scholar 

  19. L. M. Yarysheva, I. V. Chernov, L. Yu. Kabal’nova, et al., Vysokomol. Soedin., Ser. A 31, 1544 (1989).

    CAS  Google Scholar 

  20. L. M. Yarysheva, L. Yu. Pazukhina, T. A. Borodulina, et al., Vysokomol. Soedin., Ser. A 26, 2380 (1984).

    CAS  Google Scholar 

  21. L. M. Yarysheva, L. Yu. Pazukhina, N. M. Kabanov, et al., Vysokomol. Soedin., Ser. A 26, 388 (1984).

    CAS  Google Scholar 

  22. A. S. Kechek’yan, G. P. Andrianova, and V. A. Kargin, Vysokomol. Soedin., Ser. A 12, 2424 (1970).

    Google Scholar 

  23. L. M. Yarysheva, A. A. Dolgova, O. V. Arzhakova, et al., Polymer Science, Ser. A 44 (2002) [Vysokomol. Soedin., Ser. A 44, 1359 (2002)].

    Google Scholar 

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    E. G. Rukhlya, L. M. Yarysheva, A. L. Volynskii & N. F. Bakeev

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  1. E. G. Rukhlya
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  2. L. M. Yarysheva
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  3. A. L. Volynskii
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  4. N. F. Bakeev
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Corresponding author

Correspondence to E. G. Rukhlya.

Additional information

Original Russian Text © E.G. Rukhlya, L.M. Yarysheva, A.L. Volynskii, N.F. Bakeev, 2010, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2010, Vol. 52, No. 6, pp. 949–955.

This work was supported by the Russian Foundation for Basic Research, project no. 09-03-00430-a; by a Grant for the Support of Leading Scientific Schools, NSh-2467.2008.3; and by State Contract no. P1484.

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Rukhlya, E.G., Yarysheva, L.M., Volynskii, A.L. et al. The effect of strain rate on solvent crazing of poly(ethylene terephthalate) in solutions of poly(ethylene oxide) of various molecular masses. Polym. Sci. Ser. A 52, 614–620 (2010). https://doi.org/10.1134/S0965545X10060076

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  • DOI: https://doi.org/10.1134/S0965545X10060076

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