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Intermacromolecular interactions involving linear and network polyacids and nonionic polymers

  • Polyelectrolytes
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Abstract

Interactions between linear and network polymers are studied in the case when one component is a polyacid and the other component is an uncharged polymer. It is shown that, under different reaction conditions, swelling or contraction of the polymer network can be observed for the same pair of reagents. It is found that, during consideration of the formation of an interpolymer complex between network and linear polymers, a distinction should be made between a semi-interpenetrating network and a hydrogel with a modified surface. The latter forms under conditions when the linear polymer practically does not penetrate the network and the complexation occurs predominantly on the sample surface.

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References

  1. Y. Osada, Adv. Polym. Sci. 82, 3 (1987).

    Google Scholar 

  2. S. G. Starodubtsev, Vysokomol. Soedin., Ser. B 33, 5 (1991).

    CAS  Google Scholar 

  3. S. G. Starodubtsev and O. E. Filippova, Vysokomol. Soedin., Ser. B 34, 72 1992).

    CAS  Google Scholar 

  4. T. V. Budtova, I. E. Suleimenov, and S. Ya. Frenkel’, Polymer Science, Ser. B 35, 76 (1993) [Vysokomol. Soedin., Ser. B 35, 93 (1993).

    Google Scholar 

  5. N. S. Karib’yants, O. E. Filippova, and S. G. Starodubtsev, Polymer Science, Ser. B 37, 385 (1995) [Vysokomol. Soedin., Ser. B 37, 1386 (1995)].

    Google Scholar 

  6. Z. S. Nurkeeva, G. A. Mun, and V. V. Khutoryanskii, Polymer Science, Ser. B 43, 148 (2001) [Vysokomol. Soedin., Ser. B 43, 925 (2001)].

    Google Scholar 

  7. G. A. Mun, V. V. Khutoryanskii, I. K. Nam, et al., Polymer Science, Ser. B 40, 290 (1998) [Vysokomol. Soedin., Ser. B 40, 1403 (1998)].

    Google Scholar 

  8. T. V. Budtova, I. E. Suleimenov, and S. Ya. Frenkel’, Zh. Prikl. Khim. (S.-Peterburg) 70, 529 (1997).

    CAS  Google Scholar 

  9. R. Yoschida, K. Uchida, Y. Kaneko, et al., Nature (London) 374, 240 (1995).

    Article  Google Scholar 

  10. V. G. Sergeyev, O. A. Novoskoltseva, O. A. Pyshkina, et al., J. Am. Chem. Soc. 124, 11324 (2002).

    Article  CAS  Google Scholar 

  11. O. E. Philippova, D. Hourdet, R. Audebert, and A. R. Khokhlov, Macromolecules 30, 8278 (1997).

    Article  CAS  Google Scholar 

  12. I. E. Suleimenov, T. V. Budtova, E. M. Rustemova, and E. A. Bekturov, Problems of Physical Chemistry of Polyelectrolytes (Nauka, Almaty, 2007) [in Russian].

    Google Scholar 

  13. A. N. Gorban’, V. L. Dunin-Barkovskii, and E. M. Mirkes, Neuroinformatics (Nauka, Novosibirsk, 1998) [in Russian].

    Google Scholar 

  14. E. E. Ergozhin, A. B. Zezin, I. E. Suleimenov, and G. A. Mun, Hydrophilic Polymers in Nanotechnology and Nanoelectronics (Nauka, Almaty, 2008) [in Russian].

    Google Scholar 

  15. Z. S. Nurkeeva, E. M. Shaikhutdinov, A. Z. Seitov, and S. Kh. Saikieva, Vysokomol. Soedin., Ser. A 29, 932 (1987).

    CAS  Google Scholar 

  16. I. K. Nam, G. A. Mun, P. I. Urkimbaeva, and Z. S. Nurkeeva, Radiat. Phys. Chem. 66, 281 (2003).

    Article  CAS  Google Scholar 

  17. Z. S. Nurkeeva, V. A. Kasaikin, E. M. Ivleva, et al., Vysokomol. Soedin., Ser. B 31, 415 (1990).

    Google Scholar 

  18. G. A. Mun, Z. S. Nurkeeva, and V. V. Khutoryanskiy, Macromol. Chem. Phys. 200, 2136 (1999).

    Article  CAS  Google Scholar 

  19. T. V. Budtova, I. E. Suleimenov, and S. Ya. Frenkel’, Polymer Science, Ser. A 37, 646 (1995) [Vysokomol. Soedin., Ser. A 37, 147 (1995)].

    Google Scholar 

  20. E. A. Bekturov and I. E. Suleimenov, Polymer Hydrogels (Nauka, Almaty, 1998) [in Russian].

    Google Scholar 

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Correspondence to G. A. Mun.

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Original Russian Text © G.A. Mun, P.I. Urkimbaeva, I.E. Suleimenov, 2010, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2010, Vol. 52, No. 6, pp. 921–925.

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Mun, G.A., Urkimbaeva, P.I. & Suleimenov, I.E. Intermacromolecular interactions involving linear and network polyacids and nonionic polymers. Polym. Sci. Ser. A 52, 586–590 (2010). https://doi.org/10.1134/S0965545X10060039

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  • DOI: https://doi.org/10.1134/S0965545X10060039

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