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Gas-separation membranes based on interpolymer complexes of sulfonate-containing aromatic polyamides

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Abstract

The gas-separation properties of membranes prepared from sulfonate-containing aromatic polyamide and aliphatic polyamines are studied. With the use of potentiometry, IR spectroscopy, and elemental analysis, it is shown that interpolymer complexes arising in these systems are primarily stabilized by electrostatic forces, while the degree of transformation in them is dependent on the basicity of polyamine and the conditions of the interpolymer reaction. The relationship between the nature of polyamine, the composition of the interpolymer complex, and the degree of transformation in it and the gas-separation characteristics of the membranes is established.

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References

  1. M. G. D’yakova, V. A. Tverskoi, Yu. A. Fedotov, et al., USSR Inventor’s Certificate No. 1 767 860 (1992).

  2. T. Yamaguchi, L. Boetje, C. Koval, et al., Ind. Eng. Chem. Res. 34, 4071 (1995).

    Article  CAS  Google Scholar 

  3. H. Matsuyama, A. Terada, T. Nakagawara, et al., Membr. Sci. 63, 221 (1999).

    Article  Google Scholar 

  4. Y. Zhang, Z. Wang, and S. Wang, Chem. Lett., No. 4, 430 (2002).

  5. A. A. Kalashnik, E. N. Lukashkina, S. S. Frolov, et al., Polymer Science, Ser. A 37, 1088 (1995) [Vysokomol. Soedin., Ser. A 37, 1747 (1995)].

    Google Scholar 

  6. J. Tajar and I. Miller, AIChE J. 18, 78 (1972).

    Article  CAS  Google Scholar 

  7. Yu. A. Fedotov, M. I. Il’in, S. S. Gitis, et al., Polymer Science, Ser. B 37, 504 (1995) [Vysokomol. Soedin., Ser. B 37, 1929 (1995)].

    Google Scholar 

  8. A. Albert and E. Serjeant, Ionization Constants (Methuen, London, 1962; Khimiya, Moscow, 1964).

    Google Scholar 

  9. H. Morawetz, Macromolecules in Solution (Wiley, New York, 1965; Mir, Moscow, 1967).

    Google Scholar 

  10. A. B. Zezin, V. V. Lutsenko, V. B. Rogacheva, et al., Vysokomol. Soedin., Ser. A 14, 772 (1972).

    CAS  Google Scholar 

  11. G. Charlot, Les methods de la chimie analytique. Analyse quantitative minerale (Masson, Paris, 1961; Khimiya, Moscow, 1965).

    Google Scholar 

  12. V. A. Kabanov, Usp. Khim. 74, 5 (2005).

    Google Scholar 

  13. V. V. Kravchenko, E. E. Lazareva, M. G. D’yakova, et al., Polymer Science, Ser. B 39, 279 (1997) [Vysokomol. Soedin., Ser. B 39, 1253 (1997)].

    Google Scholar 

  14. G. Zundel, Hydration and Intermolecular Interaction. Infrared Investigations with Polyelectrolyte Membranes (Academic, New York, 1969; Mir, Moscow, 1972).

    Google Scholar 

  15. N. N. Smirnova, Yu. A. Fedotov, and Yu. E. Kirsh, Krit. Tekhnol. Membr., No. 8, 17 (2000).

  16. V. A. Tverskoi, V. I. Semenov, N. V. Shevlyakova, et al., Vysokomol. Soedin., Ser. A 30, 2584 (1988).

    CAS  Google Scholar 

  17. K. Okabe and M. Nakabayashi, 9579758.

  18. R. I. Jande, Diss. Abstr. Alnt. B 38, 1810 (1977).

    Google Scholar 

  19. J. Maeda and D. Paul, J. Polym. Sci., Part B: Polym. Phys. 25, 957 (1987).

    Article  CAS  Google Scholar 

  20. G. A. Polotskaya, S. A. Agranova, T. A. Antonova, and G. K. El’yashevich, Zh. Prikl. Khim. (St.-Petersburg) 70, 1371 (1997).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Vladimir State University, ul. Gor’kogo 87, Vladimir, 600000, Russia

    N. N. Smirnova

  2. ZAO Vladipor Scientific and Technical Center, Bol’shaya Nizhegorodskaya ul. 77, Vladimir, 600016, Russia

    Yu. A. Fedotov

  3. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 119571, Russia

    V. A. Tverskoi

Authors
  1. N. N. Smirnova
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  2. Yu. A. Fedotov
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  3. V. A. Tverskoi
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Correspondence to N. N. Smirnova.

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Original Russian Text © N.N. Smirnova, Yu.A. Fedotov, V.A. Tverskoi, 2010, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2010, Vol. 52, No. 4, pp. 609–614.

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Smirnova, N.N., Fedotov, Y.A. & Tverskoi, V.A. Gas-separation membranes based on interpolymer complexes of sulfonate-containing aromatic polyamides. Polym. Sci. Ser. A 52, 413–418 (2010). https://doi.org/10.1134/S0965545X10040103

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  • DOI: https://doi.org/10.1134/S0965545X10040103

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