Abstract
The interaction of 2,4-toluylene diisocyanate with open-chain analogs of crown ethers containing potassium alcoholate groups is studied, and the mechanism of stabilization of the formed O-polyisocyanate end units via intermolecular interactions is proposed. The electron delocalization in intermolecular cyclic structures may be responsible for electron-transfer processes in the polymers under study.
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References
J.-M. Lehn, Supramolecular Chemistry: Concepts and Perspectives, (VCH: New York, 1998; Nauka, Novosibirsk, 1998).
E. L. Aleksandrova, M. M. Dudkina, and A. V. Ten’kovtsev, Fiz. Tekh. Poluprovodn. (S.-Peterburg) 37, 282 (2003).
E. L. Aleksandrova, M. E. Kompman, M. M. Dudkina, et al., Fiz. Tekh. Poluprovodn. (S.-Peterburg) 38, 246 (2004).
I. M. Davletbaeva, V. F. Shkodich, E. O. Ekimova, and A. M. Gumerov, Polymer Science, Ser. A 49, 944, (2007) [Vysokomol. Soedin., Ser. A 49, 1494 (2007)].
V. O. Reikhsfel’d, L. N. Erkova, and V. L. Ruban, Practical Course on Synthetic Rubbers (Khimiya, Leningrad, 1967) [in Russian].
I. M. Davletbaeva, A. V. Ten’kovtsev, R. A. Bylinkin, et al., Zh. Prikl. Khim. 75, 1572 (2002).
R. P. Tiger, L. I. Sarynina, and S. G. Entelis, Usp. Khim. 41, 1673 (1972).
E. Liver, Electronic Spectroscopy of Inorganic Compounds (Mir, Moscow, 1987), Part 1 [in Russian].
Host Guest Complex Chemistry Macrocycles, Ed. by F. Vögtle and E. Weber (Springer-Verlag, Berlin, 1985; Mir, Moscow, 1988), p. 511.
I. M. Davletbaeva, A. M. Gumerov, V. F. Shkodich, et al., in Proceedings of European Polymer Congress, Portoroz, Slovenia, 2007, p. 180.
V. G. Matyushova, T. E. Lipatova, and Yu. S. Lipatov, Dokl. Akad. Nauk Ukr. SSR, Ser. B: Geol., Khim. Biol. Nauki, No. 11, 44 (1987).
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Original Russian Text © I.M. Davletbaeva, V.F. Shkodich, A.M. Gumerov, O.Yu. Emelina, A.V. Naumov, 2010, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2010, Vol. 52, No. 4, pp. 592–598.
This work was supported by the Russian Foundation for Basic Research, project no. 09-03-97005.
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Davletbaeva, I.M., Shkodich, V.F., Gumerov, A.M. et al. Intermolecular interactions in metal-containing polymers based on 2,4-toluylene diisocyanate and open-chain analogs of crown ethers. Polym. Sci. Ser. A 52, 392–397 (2010). https://doi.org/10.1134/S0965545X10040073
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DOI: https://doi.org/10.1134/S0965545X10040073