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Effect of an anionic emulsifier on the structure of butadiene-nitrile elastomers

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Abstract

X-ray diffraction and TMA studies show that surfactant sodium alkyl sulfonate (C15) forms one of its two LC structures (distinguished by the smallest layer periodicity) in butadiene-nitrile elastomers containing different amounts of acrylonitrile units. In this case, the surfactant serves as a structural plasticizer and facilitates a more complete selective segregation of microblocks of trans-1,4-butadiene units and, especially, of sequences of alternating trans-1,4-butadiene and acrylonitrile units.

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Authors and Affiliations

  1. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571, Russia

    L. V. Sokolova

  2. Moscow State Pedagogical University, Malaya Pirogovskaya ul. 1, Moscow, 119882, Russia

    E. V. Matukhina

Authors
  1. L. V. Sokolova
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  2. E. V. Matukhina
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Correspondence to L. V. Sokolova.

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Original Russian Text © L.V. Sokolova, E.V. Matukhina, 2010, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2010, Vol. 52, No. 4, pp. 583–591.

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Sokolova, L.V., Matukhina, E.V. Effect of an anionic emulsifier on the structure of butadiene-nitrile elastomers. Polym. Sci. Ser. A 52, 383–391 (2010). https://doi.org/10.1134/S0965545X10040061

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  • DOI: https://doi.org/10.1134/S0965545X10040061

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