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Self-assembly of ionogenic surfactants during their interaction with poly(propylenimine) dendrimers

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Abstract

The structure of complexes formed by poly(propylenimine) dendrimers of five generations and anionic micelle-forming surfactants is studied by X-ray diffraction. It is shown that, in complexes of lower generation dendrimers, the lamellar packing of surfactants is dominant. In complexes formed by dendrimers of the fourth and fifth generations, packing typical of compact dendrimer molecules prevails. This packing can be attributed to the distorted dense packing of ball-like complex species. Structural models of complexes that allow for penetration of surfactants into the dendrimer molecule and the size ratio of the aliphatic radical of a surfactant and a dendrimer are advanced.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    S. B. Zezin, O. A. Novoskol’tseva, V. B. Rogacheva & A. B. Zezin

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  1. S. B. Zezin
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  2. O. A. Novoskol’tseva
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  3. V. B. Rogacheva
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  4. A. B. Zezin
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Corresponding author

Correspondence to S. B. Zezin.

Additional information

Original Russian Text © S.B. Zezin, O.A. Novoskol’tseva, V.B. Rogacheva, A.B. Zezin, 2010, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2010, Vol. 52, No. 4, pp. 573–582.

This work was supported by the Russian Foundation for Basic Research (project no. 09-03-00488-a) and the Council for Grants of the President of the Russian Federation for Support of Leading Institutes of Higher Education (grant no. NSh-168.2008.3).

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Zezin, S.B., Novoskol’tseva, O.A., Rogacheva, V.B. et al. Self-assembly of ionogenic surfactants during their interaction with poly(propylenimine) dendrimers. Polym. Sci. Ser. A 52, 374–382 (2010). https://doi.org/10.1134/S0965545X1004005X

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  • DOI: https://doi.org/10.1134/S0965545X1004005X

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