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Thermodynamics and viscosities of dilute polymer solutions in binary solvents

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Abstract

Experiments aimed at comparison of calculated and experimental intrinsic viscosities of PS and PMMA in some binary solvents used as eluents in chromatography are performed. The intrinsic viscosities are determined in mixed solvents of different thermodynamic qualities, including a θ solvent, in a wide composition range. The analysis of the thermodynamic and rheological theoretical equations for ternary systems allowed the interpretation of anomalies observed on the experimental curves of intrinsic viscosity versus solvent composition.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31, St. Petersburg, 199004, Russia

    V. P. Budtov, N. G. Bel’nikevich & L. S. Litvinova

Authors
  1. V. P. Budtov
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  2. N. G. Bel’nikevich
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  3. L. S. Litvinova
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Correspondence to N. G. Bel’nikevich.

Additional information

Original Russian Text © V.P. Budtov, N.G. Bel’nikevich, L.S. Litvinova, 2010, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2010, Vol. 52, No. 4, pp. 561–566.

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Budtov, V.P., Bel’nikevich, N.G. & Litvinova, L.S. Thermodynamics and viscosities of dilute polymer solutions in binary solvents. Polym. Sci. Ser. A 52, 362–367 (2010). https://doi.org/10.1134/S0965545X10040036

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  • DOI: https://doi.org/10.1134/S0965545X10040036

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