Abstract
The temperature dependences of the heat capacities of hydrated acrylamide and poly(acrylamide) complexes of cobalt nitrate are studied via high-precision adiabatic calorimetry at 6 to 300–380 K. The energy of combustion is estimated via isothermic calorimetry. This evidence makes it possible to calculate thermodynamic functions C ℴ p (T), H ℴ(T) − H ℴ(0), S ℴ(T), G ℴ(T) − H ℴ(0) at 0 to 300–380 K; the standard enthalpy of combustion, ΔcH ℴ; and the thermodynamic parameters of formation, Δ f H ℴ, Δ f S ℴ, and Δ f G ℴ, of monomer and polymer complexes composed of simple compounds at 298.15 K. The results are used for the estimation of enthalpy Δpol H ℴ, entropy Δpol S ℴ, and Gibbs function Δpol G ℴ of bulk polymerization for hydrated acrylamide complexes of cobalt nitrate at 0–300 K.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. D. Pomogailo and G. I. Dzhardimalieva, Polymer Science, Ser. A 46, 250 (2004) [Vysokomol. Soedin., Ser. A 46, 437 (2004)].
G. I. Dzhardimalieva, A. D. Pomogailo, and V. A. Volpert, J. Inorg. Organomet. Polym. 12, 1 (2002).
L. P. Kholpanov, S. E. Zakiev, and A. D. Pomogailo, Polymer Science, Ser. A 48, 11 (2006) [Vysokomol. Soedin., Ser. A 48, 16 (2006)].
T. A. Bykova, B. V. Lebedev, V. N. Larina, et al., Polymer Science, Ser. A 45, 545 (2003) [Vysokomol. Soedin., Ser. A 45, 921 (2003)].
V. S. Savost’yanov, V. I. Ponomarev, A. D. Pomogailo, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 4, 762 (1990).
S. I. Evstratova, G. V. Shilov, G. I. Dzhardimalieva, et al.,Koord. Khim. 27, 778 (2001).
R. M. Varushchenko, A. I. Druzhinina, and E. L. Sorkin, J. Chem. Thermodyn. 29, 623 (1997).
V. I. Tel’noi, K. V. Kir’yanov, V. I. Ermolaev, and I. B. Rabinovich, Tr. Gor’kovsk. Gos. Univ., Khim. Khim. Tekhnol., No. 4, 3 (1975).
S. Alford and M. Dole, J. Am. Chem. Soc. 77, 4774 (1955).
G. Adam and J. U. Gibbs, J. Chem. Phys. 43, 139 (1965).
A. D. Izotov, O. V. Shebershneva, and K. S. Gavrichev, in Proceedings of All-Russia Conference on Thermal Analysis and Calorimetry, Kazan, 1996, p. 200.
V. V. Tarasov, Zh. Fiz. Khim. 24, 111 (1950).
G. I. Dzhardimalieva, A. D. Pomogailo, S. P. Davtyan, and V. I. Ponomarev, Izv. Akad. Nauk SSSR, Ser. Khim., No. 7, 1531 (1988).
S. M. Skuratov, V. P. Kolesov, and A. F. Vorob’ev, in Thermochemistry (Mosk. Gos. Univ., Moscow, 1966), Vol. 2, p. 54.
Thermal Constants of Substances, Ed. by V. P. Glushko (VINITI, Moscow, 1965–1972) [in Russian].
B. V. Lebedev and N. N. Smirnova, Chemical Thermodynamics of Polyalkanes and Polyalkenes (Nizhegorodsk. Gos. Univ., Nizhni Novgorod, 1999) [in Russian].
B. V. Lebedev, Thermochim. Acta 297, 143 (1977).
H. Sawada, Thermodynamics of Polymerization (Marcel Dekker, New York, 1976; Khimiya, Moscow, 1979).
Yu. S. Lipatov, A. E. Nesterov, T. M. Gritsenko, and R. A. Veselovskii, Handbook on Polymer Chemistry (Naukova Dumka, Kiev, 1971) [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.N. Smirnova, T.A. Bykova, V.N. Larina, T.G. Kulagina, A.D. Pomogailo, G.I. Dzhardimalieva, 2010, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2010, Vol. 52, No. 4, pp. 547–553.
Rights and permissions
About this article
Cite this article
Smirnova, N.N., Bykova, T.A., Larina, V.N. et al. Thermodynamic characteristics of hydrated acrylamide and polyacrylamide complexes of cobalt nitrate at T → 0 to 380 K. Polym. Sci. Ser. A 52, 349–355 (2010). https://doi.org/10.1134/S0965545X10040012
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0965545X10040012