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Phase diagrams and the thermodynamic Flory-Huggins interaction parameter of deformed solutions of polymers

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Abstract

It is assumed that the interaction parameter used in the Flory-Huggins theory may depend on the mechanical field. The effect of deformation on phase transitions in polymer solutions is considered under this assumption. An expression relating the thermodynamic parameter of interaction between the components to deformation conditions is proposed. Quantitative relations describing shifts in liquidus lines and spinodals of polymer-solvent systems in mechanical fields are derived.

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Authors and Affiliations

  1. Ural State University, pr. Lenina 51, Yekaterinburg, 620083, Russia

    S. A. Vshivkov

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Original Russian Text © S.A. Vshivkov, 2009, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2009, Vol. 51, No. 8, pp. 1421–1426.

This work was supported by the US Civil Research and Development Foundation (CRDF) (project no. PG07-005-02) and grants of the Ministry of Education and Science of the Russian Federation (project no. AVTsP 2.1.1/1535 Development of the Scientific Potential of the Higher School) and project NK-43P/4 Federal Special-Purpose Program “Scientific and Educational Specialists of the Innovative Russia.”

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Vshivkov, S.A. Phase diagrams and the thermodynamic Flory-Huggins interaction parameter of deformed solutions of polymers. Polym. Sci. Ser. A 51, 858–863 (2009). https://doi.org/10.1134/S0965545X09080021

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  • DOI: https://doi.org/10.1134/S0965545X09080021

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