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Immobilization of tetraphenylporphyn and its metallocomplexes on the surface of plasma-treated polypropylene

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Abstract

The immobilization of 5,10,15,20-tetraphenylporphyn and its zinc and manganese complexes on the surface of polypropylene modified by plasmachemical treatment and subsequent grafting copolymerization of acrylamide or 4-vinylpyridine has been studied by multiple attenuated total reflection FTIR spectroscopy, electronic absorption spectroscopy, and atomic force microscopy. It has been demonstrated that the immobilized molecules of tetraphenylporphyn and its metallocomplexes are active in the photosensitized generation of singlet oxygen to the gas phase.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, pr. F. Engel’sa 7, Ivanovo, 153000, Russia

    V. A. Titov, T. A. Ageeva, T. G. Shikova & V. V. Rybkin

  2. Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya 1, Ivanovo, 153045, Russia

    E. S. Krivykh & I. A. Vershinina

  3. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia

    A. B. Solov’eva & V. A. Timofeeva

  4. Department of Chemical Engineering, Chungnam National University, Daejeon, 305-764, Korea

    H. -S. Choi

Authors
  1. V. A. Titov
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  2. E. S. Krivykh
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  3. T. A. Ageeva
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  4. T. G. Shikova
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  5. A. B. Solov’eva
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  6. V. A. Timofeeva
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  7. I. A. Vershinina
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  8. V. V. Rybkin
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  9. H. -S. Choi
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Corresponding author

Correspondence to T. A. Ageeva.

Additional information

Original Russian Text © V.A. Titov, E.S. Krivykh, T.A. Ageeva, T.G. Shikova, A.B. Solov’eva, V.A. Timofeeva, I.A. Vershinina, V.V. Rybkin, H.-S. Choi, 2008, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2008, Vol. 50, No. 8, pp. 1454–1462.

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Titov, V.A., Krivykh, E.S., Ageeva, T.A. et al. Immobilization of tetraphenylporphyn and its metallocomplexes on the surface of plasma-treated polypropylene. Polym. Sci. Ser. A 50, 841–847 (2008). https://doi.org/10.1134/S0965545X08080038

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  • DOI: https://doi.org/10.1134/S0965545X08080038

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