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Anharmonicity and the elementary event of plastic deformation of amorphous polymers and glasses

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Abstract

The critical displacement of an excited atom (group of atoms) corresponding to the maximum in the interatomic attraction force plays an important part in the elementary event of plastic deformation of glassy solids. As a result of considerable departure of the excited kinetic unit from the equilibrium position and the nonlinearity of the interatomic interaction force, the microdeformation in the elementary event turns out to be a function of the degree of anharmonicity (Grüneisen parameter).

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References

  1. The Physics of Glassy Polymers, Ed. by R. N. Haward and B. Y. Young (Chapman and Hall, London, 1997).

    Google Scholar 

  2. Z. H. Stachurski, Prog. Polym. Sci. 22, 407 (1997).

    Article  CAS  Google Scholar 

  3. S. V. Shenogin, G. W. H. Hohne, O. B. Salamatina, et al., Polymer Science, Ser. A 46, 21 (2004) [Vysokomol. Soedin., Ser. A 46, 30 (2004)].

    Google Scholar 

  4. N. N. Peschanskaya, V. A. Bershtein, and V. A. Stepanov, Fiz. Tverd. Tela (Leningrad) 20, 3371 (1978).

    CAS  Google Scholar 

  5. A. B. Sinani and V. A. Stepanov, Mekh. Kompoz. Mater. (Rizh. Politekh. Inst.), No. 1, 109 (1981).

  6. A. S. Argon, Pure Appl. Chem. 43, 247 (1975).

    CAS  Google Scholar 

  7. S. A. Arzhakov, N. F. Bakeev, and V. A. Kabanov, Vysokomol. Soedin., Ser. A 15, 1154 (1973).

    CAS  Google Scholar 

  8. M. S. Arzhakov, G. M. Lukovkin, and S. A. Arzhakov, Dokl. Akad. Nauk 369, 629 (1999).

    CAS  Google Scholar 

  9. V. N. Shogenov, G. V. Kozlov, and A. K. Mikitaev, Vysokomol. Soedin., Ser. A 31, 1766 (1989).

    CAS  Google Scholar 

  10. G. V. Kozlov and D. S. Sanditov, Anharmonic Effects and Mechanical Properties of Polymers (Nauka, Novosibirsk, 1994) [in Russian].

    Google Scholar 

  11. Structural Levels of Plastic Deformation and Fracture, Ed. by V. E. Panin (Nauka, Novosibirsk, 1990) [in Russian].

    Google Scholar 

  12. D. S. Sanditov, Dokl. Akad. Nauk 390, 209 (2003).

    Google Scholar 

  13. D. S. Sanditov, Polymer Science, Ser. A 47, 289 (2005) [Vysokomol. Soedin., Ser. A 47, 478 (2005)].

    Google Scholar 

  14. D. S. Sanditov, Dokl. Akad. Nauk 403, 210 (2005).

    Google Scholar 

  15. Ya. I. Frenkel, An Introduction to the Theory of Metals (Gostekhizdat, Leningrad, 1948) [in Russian].

    Google Scholar 

  16. A. I. Burshtein, Molecular Physics (Nauka, Novosibirsk, 1986) [in Russian].

    Google Scholar 

  17. G. Leibfried, Gittertheorie der mechanischen und thermischen Eigenschaften der Kristalle (Springer, Berlin, 1955; Fizmatgiz, Moscow, 1963).

    Google Scholar 

  18. V. A. Petrov, A. Ya. Bashkarev, and V.I. Vettegren’, Physical Principles of Forecasting of Durability of Structural Materials (Politekhnika, St. Petersburg, 1993) [in Russian].

    Google Scholar 

  19. S. N. Zhurkov and V.A. Petrov, Dokl. Akad. Nauk SSSR 239, 1316 (1978).

    Google Scholar 

  20. D. S. Sanditov and V. V. Mantatov, Fiz. Khim. Stekla 9, 287 (1983).

    CAS  Google Scholar 

  21. B. D. Sanditov and V.V. Mantatov, Nonlinear Character of Intermolecular Interactions in Noncrystalline Solids (Buryat. Gos. Univ., Ulan-Ude, 2001) [in Russian].

    Google Scholar 

  22. Yu. K. Godovskii, Thermal Physics of Polymers (Khimiya, Moscow, 1982) [in Russian].

    Google Scholar 

  23. R. W. Warfield, Makromol. Chem. 175, 3285 (1974).

    Article  CAS  Google Scholar 

  24. Y. Wada, A. Itani, T. Nishi, and S. Nagai, J. Polym. Sci., Part A-2 7, 201 (1969).

    Article  CAS  Google Scholar 

  25. D. S. Sanditov and V. V. Mantatov, Vysokomol. Soedin., Ser. B 32, 869 (1990).

    CAS  Google Scholar 

  26. V. N. Belomestnykh and E. P. Tesleva, Zh. Tekh. Fiz. 74(8), 140 (2004).

    Google Scholar 

  27. B. D. Sanditov, Sh. B. Tsydypov, D. S. Sanditov, and V. V. Mantatov, Polymer Science, Ser. B 48, 173 (2006) [Vysokomol. Soedin., Ser. B 48, 1198 (2006)].

    Article  Google Scholar 

  28. D. S. Sanditov and G. M. Bartenev, Physical Properties of Disordered Structures (Nauka, Novosibirsk, 1982) [in Russian].

    Google Scholar 

  29. G. M. Bartenev and D. S. Sanditov, Dokl. Akad. Nauk SSSR 176, 66 (1967).

    CAS  Google Scholar 

  30. G. M. Bartenev, Structure and Mechanical Properties of Inorganic Glasses (Stroiizdat, Moscow, 1966) [in Russian].

    Google Scholar 

  31. V. V. Tarasov, New Problems of Glass Physics (Stroiizdat, Moscow, 1959) [in Russian].

    Google Scholar 

  32. G. P. Andrianova and V. A. Kargin, Vysokomol. Soedin., Ser. A 12, 3 (1970).

    CAS  Google Scholar 

  33. G. Adam and J. H. Gibbs, J. Chem. Phys. 43, 139 (1965).

    Article  CAS  Google Scholar 

  34. G. V. Kozlov and D. S. Sanditov, Vysokomol. Soedin., Ser. B 34, 67 (1992).

    CAS  Google Scholar 

  35. R. R. Abdul’manov, V.A. Vettegren’, and V. M. Vorob’ev, Vysokomol. Soedin., Ser. A 26, 1830 (1984).

    CAS  Google Scholar 

  36. J. M. Ziman, Electrons and Phonons (Oxford Univ. Press, London, 1963).

    Google Scholar 

  37. J. M. Ziman, Principles of the Theory of Solids (Cambridge Univ. Press, Cambridge, 1964; Mir, Moscow, 1966).

    Google Scholar 

  38. G. V. Kozlov, R. A. Shetov, and A. K. Mikitaev, Dokl. Akad. Nauk SSSR 290, 885 (1986).

    CAS  Google Scholar 

  39. M. I. Bessonov and A. P. Rudakov, Vysokomol. Soedin., Ser. B 13, 509 (1971).

    CAS  Google Scholar 

  40. D. S. Sanditov and V.V. Mantatov, Vysokomol. Soedin., Ser. B 32, 119 (1991).

    Google Scholar 

  41. S. V. Nemilov, Fiz. Khim. Stekla 4, 662 (1978).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Buryat State University, ul. Smolina 24a, Ulan-Ude, 670000, Buryatia, Russia

    B. D. Sanditov, V. V. Mantatov & D. S. Sanditov

  2. Department of Physics Problems, Buryat Research Center, Siberian Branch, Russian Academy of Sciences, ul. Sakh″yanovoi 8, Ulan-Ude, 670047, Buryatia, Russia

    D. S. Sanditov

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  1. B. D. Sanditov
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  2. V. V. Mantatov
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  3. D. S. Sanditov
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Correspondence to B. D. Sanditov.

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Original Russian Text © B.D. Sanditov, V.V. Mantatov, D.S. Sanditov, 2007, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2007, Vol. 49, No. 9, pp. 1679–1688.

This work was supported by the Russian Foundation for Basic Research, project no. 05-01-00071a.

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Sanditov, B.D., Mantatov, V.V. & Sanditov, D.S. Anharmonicity and the elementary event of plastic deformation of amorphous polymers and glasses. Polym. Sci. Ser. A 49, 1026–1033 (2007). https://doi.org/10.1134/S0965545X07090106

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  • DOI: https://doi.org/10.1134/S0965545X07090106

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