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Hydrolytic degradation and thermal stability of poly(naphthylimides) based on naphthalene-1,4,5,8-tetracarboxylic dianhydride and bis(naphthalic anhydrides)

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Abstract

The molecular properties of a number of new poly(naphthylimides) derived from naphthalene-1,4,5,8-tetracarboxylic dianhydride and bis(naphthalic anhydrides) have been studied. On the basis of hydrodynamic studies of the polymers at various stages of their thermal degradation in 96% H2SO4 and thermogravimetric measurements, the hydrolytic stability and thermooxidative resistance of the polymers have been compared. A correlation between the experimental data and the chemical structure of molecular chains has been established.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31, St. Petersburg, 199004, Russia

    O. V. Okatova, N. N. Ul’yanova & P. N. Lavrenko

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    E. G. Bulycheva, L. B. Elshina & A. L. Rusanov

Authors
  1. O. V. Okatova
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  2. N. N. Ul’yanova
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  3. E. G. Bulycheva
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  4. L. B. Elshina
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  5. A. L. Rusanov
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  6. P. N. Lavrenko
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Additional information

Original Russian Text © O.V. Okatova, N.N. Ul’yanova, E.G. Bulycheva, L.B. Elshina, A.L. Rusanov, P.N. Lavrenko, 2007, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2007, Vol. 49, No. 6, pp. 1065–1071.

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Okatova, O.V., Ul’yanova, N.N., Bulycheva, E.G. et al. Hydrolytic degradation and thermal stability of poly(naphthylimides) based on naphthalene-1,4,5,8-tetracarboxylic dianhydride and bis(naphthalic anhydrides). Polym. Sci. Ser. A 49, 716–721 (2007). https://doi.org/10.1134/S0965545X07060132

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  • DOI: https://doi.org/10.1134/S0965545X07060132

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