Skip to main content
SpringerLink
Log in

Transport parameters of glassy polymers: Effect of occupied and accessible volumes

  • Structure, Properties
  • Published:
Polymer Science Series A Aims and scope Submit manuscript

Abstract

The occupied and accessible volumes have been calculated for 32 polyimides of various structures. The calculation data have been compared with the experimentally measured transport parameters for one polymer-various gases and one gas-various polymers systems. The correlation coefficients have been estimated as 90–98%. The transport parameters plotted as a function of the Kuhn segment are described by curves with maxima. The best transport characteristics are exhibited by polymers with Kuhn segment lengths of 60–80 Å.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Yu. Alent’ev, I. A. Ronova, B. V. Shchukin, and Yu. P. Yampol’skii, Polymer Science, Ser. A 48, 1120 (2006) [Vysokomol. Soedin., Ser. A 48, 1876 (2006)].

    Article  Google Scholar 

  2. Ya. I. Frenkel’, Kinetic Theory of Liquids (Akad. Nauk SSSR, Moscow, 1958) [in Russian].

    Google Scholar 

  3. M. H. Cohen and D. Turnbull, J. Chem. Phys. 31, 1164 (1959).

    Article  CAS  Google Scholar 

  4. R. Simha and R. F. Boyer, J. Chem. Phys. 37, 1008 (1962).

    Article  Google Scholar 

  5. A. Bondi, Physical Properties of Molecular Crystals, Liquids, and Glasses (Wiley, New York, 1968).

    Google Scholar 

  6. Y. Hirayama, T. Yoshinaga, Y. Kusuki, et al., J. Membr. Sci. 111, 169 (1996).

    Article  CAS  Google Scholar 

  7. V. V. Teplyakov and S. G. Durgar’yan, Vysokomol. Soedin., Ser. A 26, 1498 (1984).

    CAS  Google Scholar 

  8. V. V. Teplyakov and S. G. Durgar’yan, Vysokomol. Soedin., Ser. A 26, 2159 (1984).

    CAS  Google Scholar 

  9. J. Y. Park and D. R. Paul, J. Membr. Sci. 125, 23 (1997).

    Article  CAS  Google Scholar 

  10. D. N. Theodorou, in Diffusion in Polymers, Ed. by P. Neogi (Marcel Dekker, New York, 1996), p. 67.

    Google Scholar 

  11. D. Hofmann, L. Fritz, J. Ulbricht, et al., Macromol. Theory Simul. 9, 293 (2001).

    Article  Google Scholar 

  12. D. Hofmann, M. Heuchel, Yu. Yampolskii, et al., Macromolecules 35, 2129 (2002).

    Article  CAS  Google Scholar 

  13. E. M. Rozhkov, B. V. Schukin, and I. A. Ronova, Eur. J. Chem. 1, 402 (2003).

    CAS  Google Scholar 

  14. M. J. S. Dewar, E. F. Zoebisch, E. F. Healy, and J. J. Stewart, J. Am. Chem. Soc. 107, 3903 (1985).

    Google Scholar 

  15. A. A. Askadskii and V. I. Kondrashchenko, Computer-Based Materiology of Polymers (Nauchnyi Mir, Moscow, 1999) [in Russian].

    Google Scholar 

  16. S. S. A. Pavlova, I. A. Ronova, G. I. Timofeeva, and L. V. Dubrovina, J. Polym. Sci., Part B: Polym. Phys. 31, 725 (1993).

    Article  Google Scholar 

  17. I. A. Ronova and S. S. A. Pavlova, High Perform. Polym. 10, 309 (1998).

    Article  CAS  Google Scholar 

  18. A. Yu. Alentiev, I. A. Ronova, and Yu. P. Yampolskii, in Proceedings of 2 Russian Kargin Symposium “Chemistry and Physics of Polymers in XXI Century”, St. Petersburg, 2000, p. S1–9.

  19. K. Tanaka, H. Kita, M. Okono, and K. Okamoto, Polymer 33, 585 (1992).

    Article  CAS  Google Scholar 

  20. S. A. Stern, Y. Mi, H. Yamamoto, and A. St. Clair, J. Polym. Sci., Part B: Polym. Phys. 27, 1887 (1989).

    Article  CAS  Google Scholar 

  21. K. Tanaka, M. Okano, H. Kita, et al., Polym. J. (Tokyo) 26, 1186 (1994).

    CAS  Google Scholar 

  22. K. Tanaka, H. Kita, K. Okamoto, et al., J. Membr. Sci. 47, 203 (1989).

    Article  CAS  Google Scholar 

  23. K. Tanaka, H. Kita, K. Okamoto, et al., Polym. J. (Tokyo) 22, 381 (1990).

    CAS  Google Scholar 

  24. K. Okamoto, K. Tanaka, H. Kita, et al., Polym. J. (Tokyo) 24, 451 (1992).

    CAS  Google Scholar 

  25. K. Hirayama, T. Yoshinaga, Y. Kusuki, et al., J. Membr. Sci. 111, 169 (1996).

    Article  CAS  Google Scholar 

  26. K. Tanaka, M. Okano, H. Toshino, and K. Okamoto, J. Polym. Sci., Part B: Polym. Phys. 30, 907 (1992).

    Article  CAS  Google Scholar 

  27. A. Stern, Y. Mi, H. Yamamoto, and A. St. Clair, J. Polym. Sci., Part B: Polym. Phys. 27, 1887 (1989).

    Article  CAS  Google Scholar 

  28. M. R. Coleman and W. J. Koros, J. Membr. Sci. 50, 285 (1990).

    Article  CAS  Google Scholar 

  29. K. Matsumoto, P. Xu, and T. Nishikimi, J. Membr. Sci. 81, 15 (1993).

    Article  CAS  Google Scholar 

  30. D. R. Walker and W. J. Koros, J. Membr. Sci. 55, 99 (1991).

    Article  CAS  Google Scholar 

  31. K. Tanaka, Y. Osada, H. Kita, and K. Okamoto, J. Polym. Sci., Part B: Polym. Phys. 33, 1907 (1995).

    Article  CAS  Google Scholar 

  32. M. Langsam and W. F. Burgoyne, J. Polym. Sci., Part A: Polym. Chem. 31, 909 (1993).

    Article  CAS  Google Scholar 

  33. Database “Gas Separation Parameters of Glassy Polymers”. Informregistr, 1998, No. 3585.

  34. K. Tanaka, M. Katsuba, K. Okamoto, et al., Bull. Chem. Soc. Jpn. 65, 1891 (1992).

    Article  CAS  Google Scholar 

  35. J. Kristiak, J. Bartos, K. Kristiakova, et al., Phys. Rev. B: Condens. Matter 49, 6601 (1994).

    CAS  Google Scholar 

  36. R. Srithawatpong, Z. L. Peng, B. G. Oslon, et al., J. Polym. Sci., Part B: Polym. Phys. 37, 2754 (1999).

    Article  CAS  Google Scholar 

  37. V. I. Gol’danskii, V. A. Onishchuk, V. P. Shantarovich, et al., Khim. Fiz. 7, 616 (1988).

    CAS  Google Scholar 

  38. M. R. Pixton and D. R. Paul, in Polymeric Gas Separation Membranes, Ed. by D. R. Paul and Yu. P. Yampolskii (CRC, Boca Raton, 1994), p. 83.

    Google Scholar 

  39. A. Yu. Alentiev and Yu. P. Yampolskii, J. Membr. Sci. 206, 291 (2002).

    Article  CAS  Google Scholar 

  40. C. Nagel, K. Guenther-Schade, D. Fritsch, et al., Macromolecules 35, 2071 (2002).

    Article  CAS  Google Scholar 

  41. J. S. Vrentas and J. L. Duda, J. Polym. Sci., Part B: Polym. Phys. 15, 403, 417 (1977).

    CAS  Google Scholar 

  42. T. Miyamoto and K. Shibayama, J. Appl. Phys. 44, 5372 (1973).

    Article  CAS  Google Scholar 

  43. D. Hofmann, in Proceedings of 3rd International Workshop “Molecular Modeling in Membrane Research”, Teltow, 2002.

  44. Q. Deng and Y. C. Jean, Macromolecules 26, 30 (1993).

    Article  CAS  Google Scholar 

  45. G. Dlubek, A. P. Clarke, H. M. Fretwell, et al., Phys. Status Solidi A 157, 351 (1996).

    Article  CAS  Google Scholar 

  46. V. P. Shantarovich, I. B. Kevdina, Yu. P. Yampolskii, and A. Yu. Alentiev, Macromolecules 33, 7453 (2000).

    Article  CAS  Google Scholar 

  47. Y. Yampolskii, D. Wiley, and C. Maher, J. Appl. Polym. Sci. 76, 552 (2000).

    Article  CAS  Google Scholar 

  48. W. J. Koros and G. K. Fleming, J. Membr. Sci. 82, 1 (1993).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    I. A. Ronova & A. R. Khokhlov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    B. V. Shchukin

Authors
  1. I. A. Ronova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. R. Khokhlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. V. Shchukin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © I.A. Ronova, A.R. Khokhlov, B. V. Shchukin, 2007, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2007, Vol. 49, No. 5, pp. 796–812.

This study was supported by the INTAS Foundation, project no. 0.1-0172.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ronova, I.A., Khokhlov, A.R. & Shchukin, B.V. Transport parameters of glassy polymers: Effect of occupied and accessible volumes. Polym. Sci. Ser. A 49, 517–531 (2007). https://doi.org/10.1134/S0965545X07050057

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965545X07050057

Keywords

Search

Navigation