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Interaction of polystyrene and fullerene C60 in benzene: Composition and molecular properties of the product

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Abstract

The molecular properties and composition of fullerene-containing polystyrenes prepared through evaporation of solvent from the combined solution of a polymer and C60 in benzene have been studied by viscometry, translational isothermal diffusion, GPC, UV spectroscopy, and electrooptical Kerr effect measurements. With this procedure of C60 introduction into the polymer, a partial depolymerization of the parent polystyrene takes place. It has been shown that the composites contain fullerene in two forms: a smaller part of C60 is bound to macromolecules, while a larger part of C60 is incorporated into the composition of low-molecularmass adducts—the products arising from the interaction of fullerene with fullerene-induced depolymerized polystyrene.

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Authors and Affiliations

  1. Fock Institute of Physics, St. Petersburg State University, Ul’yanovskaya ul. 1, Petrodvorets, 198504, Russia

    N. P. Yevlampieva, I. I. Zaitseva & E. I. Ryumtsev

  2. Federal State Unitary Enterprise, Research Institute of Synthetic Rubber, Gapsal’skaya ul. 1, St. Petersburg, 198035, Russia

    T. S. Dmitrieva

  3. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31, St. Petersburg, 199004, Russia

    E. Yu. Melenevskaya

Authors
  1. N. P. Yevlampieva
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  2. T. S. Dmitrieva
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  3. E. Yu. Melenevskaya
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  4. I. I. Zaitseva
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  5. E. I. Ryumtsev
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Original Russian Text © N.P. Yevlampieva, T.S. Dmitrieva, E.Yu. Melenevskaya, I.I. Zaitseva, E.I. Ryumtsev, 2007, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2007, Vol. 49, No. 3, pp. 447–455.

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Yevlampieva, N.P., Dmitrieva, T.S., Melenevskaya, E.Y. et al. Interaction of polystyrene and fullerene C60 in benzene: Composition and molecular properties of the product. Polym. Sci. Ser. A 49, 284–291 (2007). https://doi.org/10.1134/S0965545X0703008X

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  • DOI: https://doi.org/10.1134/S0965545X0703008X

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