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Transport properties of polyphenylquinoxalines

  • Structure, Properties
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Abstract

The correlation between chemical structure and gas transport properties is considered for a new class of membrane materials based on structurally similar polyphenylquinoxalines that are characterized by different numbers of flexible-O-ether bonds in the repeating unit and different chain rigidities. Permeability, diffusion, and solubility coefficients have been estimated for the gases H2, He, O2, N2, CO, CO2, and CH4; separation factors for various gas pairs have been determined. For the materials with a similar level of cohesive energy density, which characterizes interchain interactions, permeability decreases with a decrease in chain rigidity, whereas selectivity of gas separation increases.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    M. N. Vidyakin, Yu. N. Lazareva, Yu. P. Yampolskii & A. Yu. Alentiev

  2. National Autonomous University of Mexico, 04510, Mexico City, DF, Mexico

    D. Yu. Likhachev

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    A. L. Rusanov

  4. United Research and Development Centre, Leninskii pr. 66/1, str. 3, Moscow, 119333, Russia

    O. V. Kozlova

Authors
  1. M. N. Vidyakin
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  2. Yu. N. Lazareva
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  3. Yu. P. Yampolskii
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  4. A. Yu. Alentiev
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  5. D. Yu. Likhachev
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  6. A. L. Rusanov
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  7. O. V. Kozlova
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Additional information

Original Russian Text © M.N. Vidyakin, Yu.N. Lazareva, Yu.P. Yampolskii, A. Yu. Alentiev, D.Yu. Likhachev, A.L. Rusanov, O.V. Kozlova, 2006, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2006, Vol. 48, No. 6, pp. 933–938.

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Vidyakin, M.N., Lazareva, Y.N., Yampolskii, Y.P. et al. Transport properties of polyphenylquinoxalines. Polym. Sci. Ser. A 48, 596–600 (2006). https://doi.org/10.1134/S0965545X0606006X

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  • DOI: https://doi.org/10.1134/S0965545X0606006X

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