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Complexation of Fe3+, Cu2+, and Cr3+ β-diketonates with poly(urethane) and poly(methyl methacrylate) in semi-interpenetrating networks: Effect on phase separation

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Abstract

Complexation of iron, copper, and chromium β-diketonates with poly(urethane) and poly(methyl methacrylate) in semi-interpenetrating polymer networks was studied by IR spectroscopy and ESR using various paramagnetic probes. It was shown that types of complexes arising in semi-interpenetrating polymer networks depend on the central metal ion in a chelate. In the networks containing iron and copper β-diketonates, formation of complexes between chelates of these metals and donor groups of PUR and PMMA promotes mutual penetration of poly(urethane) and poly(methyl methacrylate) phases. As a consequence, the degree of their separation decreases and the interphase region widens.

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Khar’kovskoe sh. 48, Kiev, 02160, Ukraine

    Yu. S. Lipatov, L. F. Kosyanchuk, N. V. Kozak, N. V. Yarovaya & G. Ya. Menzheres

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  1. Yu. S. Lipatov
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  2. L. F. Kosyanchuk
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  3. N. V. Kozak
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  4. N. V. Yarovaya
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  5. G. Ya. Menzheres
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Original Russian Text © Yu.S. Lipatov, L.F. Kosyanchuk, N.V. Kozak, N.V. Yarovaya, G.Ya. Menzheres, 2006, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2006, Vol. 48, No. 4, pp. 616–623.

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Lipatov, Y.S., Kosyanchuk, L.F., Kozak, N.V. et al. Complexation of Fe3+, Cu2+, and Cr3+ β-diketonates with poly(urethane) and poly(methyl methacrylate) in semi-interpenetrating networks: Effect on phase separation. Polym. Sci. Ser. A 48, 388–394 (2006). https://doi.org/10.1134/S0965545X06040079

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  • DOI: https://doi.org/10.1134/S0965545X06040079

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