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Macromolecular metal complexes with transition-metal ions: Structure of a polymer and efficiency of complexation

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Abstract

A quantitative method of estimating the efficiency of formation of macromolecular metal complexes of carboxyl-containing (co)polymers with transition-metal ions in dilute solutions was developed. This method is based on the luminescence quenching of luminescently labeled macromolecules by transition-metal ions. With the use of this method, the effect of the chemical (including isomeric) structure of carboxyl-containing (co)polymers and external conditions on the stability of macromolecular metal complexes based on copper, nickel, and silver ions was assessed. With consideration for the data obtained, a targeted variation in the functional characteristics of macromolecular metal complexes may be accomplished.

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References

  1. A. V. Finkel’shtein and O. B. Ptitsyn, Protein Physics (Knizhnyi Dom “Universitet,” Moscow, 2002) [in Russian].

    Google Scholar 

  2. A. N. Ulakhovich, Soros. Obrazov. Zh., No. 8, 27 (1997).

  3. A. D. Pomogailo and I. E. Uflyand, Macromolecular Metallochelates (Khimiya, Moscow, 1991) [in Russian].

    Google Scholar 

  4. A. D. Pomogailo, I. E. Uflyand, and E. F. Vainshtein, Usp. Khim. 64, 913 (1995).

    CAS  Google Scholar 

  5. A. D. Pomogailo, Immobilized Polymeric Metallocomplex Catalysts (Nauka, Moscow, 1988) [in Russian].

    Google Scholar 

  6. K. M. Saldadze and V. D. Kopylova-Valova, Complexing Ionites (Complexites) (Khimiya, Moscow, 1980) [in Russian].

    Google Scholar 

  7. E. V. Anufrieva, M. G. Krakovyak, T. D. Anan’eva, et al., Vysokomol. Soedin., Ser. A 40, 1847 (1998) [Polymer Science, Ser. A 40, 1146 (1998)].

    CAS  Google Scholar 

  8. E. V. Anufrieva, T. N. Nekrasova, T. D. Anan’eva, et al., Vysokomol. Soedin., Ser. A 42, 994 (2000) [Polymer Science, Ser. A 42, 654 (2000)].

    CAS  Google Scholar 

  9. E. V. Anufrieva, T. N. Nekrasova, M. G. Krakovyak, et al., Vysokomol. Soedin., Ser. A 43, 875 (2001) [Polymer Science, Ser. A 43, 560 (2001)].

    CAS  Google Scholar 

  10. E. V. Anufrieva and Yu. Ya. Gotlib, Adv. Polym. Sci. 40, 1 (1981).

    CAS  Google Scholar 

  11. E. V. Anufrieva, R. A. Gromova, V. B. Lushchik, et al., Vysokomol. Soedin., Ser. B 38, 1614 (1996) [Polymer Science, Ser. B 38, 368 (1996)].

    CAS  Google Scholar 

  12. A. N. Terenin, Photonics of Dye Molecules (Nauka, Leningrad, 1967) [in Russian].

    Google Scholar 

  13. E. E. Ergozhin, B. R. Tausarova, and R. B. Sarieva, Vysokomol. Soedin., Ser. B 34, 22 (1992).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31, St. Petersburg, 199004, Russia

    V. D. Pautov, E. V. Anufrieva, T. D. Anan’eva, V. B. Lushchik, T. N. Nekrasova & R. Yu. Smyslov

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  1. V. D. Pautov
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  2. E. V. Anufrieva
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  3. T. D. Anan’eva
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  4. V. B. Lushchik
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  5. T. N. Nekrasova
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  6. R. Yu. Smyslov
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Additional information

Original Russian Text © V.D. Pautov, E.V. Anufrieva, T.D. Anan’eva, V.B. Lushchik, T.N. Nekrasova, R.Yu. Smyslov, 2006, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2006, Vol. 48, No. 2, pp. 299–308.

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Pautov, V.D., Anufrieva, E.V., Anan’eva, T.D. et al. Macromolecular metal complexes with transition-metal ions: Structure of a polymer and efficiency of complexation. Polym. Sci. Ser. A 48, 183–191 (2006). https://doi.org/10.1134/S0965545X06020131

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  • DOI: https://doi.org/10.1134/S0965545X06020131

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