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Electrostatic long-range and short-range interactions in linear poly(allylamine hydrochloride) chains

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Abstract

The efficiencies of two azo initiators in the polymerization of allylamine salts in water and organic solvents were compared. The hydrodynamic and molecular characteristics of poly(allylamine hydrochloride) in 0.1 M NaCl in the molecular mass range M×10−3=18−65 were studied, and the scaling relationships were derived for the intrinsic viscosity ([η]=7.65×10−3 M 0.8±0.1), translational diffusion coefficient (D 0=2.41×10−4 M −(0.59±0.05)), and velocity sedimentation coefficient (s 0=2.77×10−15 M 0.41±0.05). The hydrodynamic data were interpreted in terms of electrostatic long-range and short-range interactions. The equilibrium rigidity of poly(allylamine hydrochloride) chains in 0.1 M NaCl and its structural and electrostatic constituents were quantitatively estimated. It was shown that the conformation of poly(allylamine hydrochloride) chains in pure water is close to rodlike.

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Authors and Affiliations

  1. Fock Research Institute of Physics, St. Petersburg State University, ul. Ul’yanovskaya 1, Petrodvorets, 198504, Russia

    G. M. Pavlov

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31, St. Petersburg, 199004, Russia

    E. V. Korneeva, I. I. Gavrilova, N. N. Tarasova & E. F. Panarin

Authors
  1. G. M. Pavlov
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  2. E. V. Korneeva
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  3. I. I. Gavrilova
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  4. N. N. Tarasova
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  5. E. F. Panarin
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Additional information

Original Russian Text © G.M. Pavlov, E.V. Korneeva, I.I. Gavrilova, N.N. Tarasova, E.F. Panarin, 2006, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2006, Vol. 48, No. 2, pp. 292–298.

This work was supported in part by the Ministry of Industry, Science, and Technologies of the Russian Federation, grant MSh 1823.2003.3.

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Pavlov, G.M., Korneeva, E.V., Gavrilova, I.I. et al. Electrostatic long-range and short-range interactions in linear poly(allylamine hydrochloride) chains. Polym. Sci. Ser. A 48, 177–182 (2006). https://doi.org/10.1134/S0965545X0602012X

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  • DOI: https://doi.org/10.1134/S0965545X0602012X

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