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Phase transitions in solutions of polystyrene with poly(methyl methacrylate) and polybutadiene under deformation

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Abstract

By the cloud point and static sorption methods, phase diagrams are constructed and the concentration and temperature dependences of the Gibbs free energy of mixing and the interaction parameter are determined under static conditions and in a shear field for the poly(methyl methacrylate)-polystyrene-ethyl acetate, polystyrene-polybutadiene-toluene, polystyrene-polybutadiene, poly(methyl methacrylate)-polystyrene, poly(methyl methacrylate)-ethyl acetate, and polystyrene-ethyl acetate systems. Phase separation in the systems both under heating and cooling, as well as coexistence of three phases, is observed in the polystyrene-poly(methyl methacrylate)-ethyl acetate system. Deformation changes the phase separation temperature by 30–40 K.

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Authors and Affiliations

  1. Ural State University, pr. Lenina 51, Yekaterinburg, 620083, Russia

    E. V. Rusinova, L. V. Adamova & S. A. Vshivkov

Authors
  1. E. V. Rusinova
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  2. L. V. Adamova
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  3. S. A. Vshivkov
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Additional information

Original Russian Text © E.V. Rusinova, L.V. Adamova, S.A. Vshivkov, 2006, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2006, Vol. 48, No. 2, pp. 271–276.

This work was supported by the Civilian Research and Development Foundation (US) (grant no. EK-005-XI).

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Rusinova, E.V., Adamova, L.V. & Vshivkov, S.A. Phase transitions in solutions of polystyrene with poly(methyl methacrylate) and polybutadiene under deformation. Polym. Sci. Ser. A 48, 159–163 (2006). https://doi.org/10.1134/S0965545X0602009X

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  • DOI: https://doi.org/10.1134/S0965545X0602009X

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