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Electrophosphorescence of aromatic polyimides doped with platinum porphyrins

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Abstract

The mechanism of electroluminescence in polymeric thin-layer devices based on aromatic polyimides and various molecular complexes of Pt porphyrins as heavy-atom-containing luminophores was studied. On the basis of spectral and electron-hole transport properties of aromatic polyimides and Pt porphyrins, as well as the current concepts adopted in polymer photonics, the processes of singlet-singlet and triplet-triplet energy transfer in the examined single-layer systems aromatic PI-Pt porphyrin with a high electrophosphorescence quantum yield exceeding 2% are discussed.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    E. I. Mal’tsev, M. A. Brusentseva, D. A. Lypenko, S. V. Novikov & A. V. Vannikov

  2. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 119571, Russia

    V. D. Rumyantseva & A. F. Mironov

  3. Karpov Institute of Physical Chemistry, Vorontsovo pole 10, Moscow, 105064, Russia

    V. I. Berendyaev

Authors
  1. E. I. Mal’tsev
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  2. M. A. Brusentseva
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  3. V. D. Rumyantseva
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  4. D. A. Lypenko
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  5. V. I. Berendyaev
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  6. A. F. Mironov
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  7. S. V. Novikov
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  8. A. V. Vannikov
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Additional information

Original Russian Text © E.I. Mal’tsev, M.A. Brusentseva, V.D. Rumyantseva, D.A. Lypenko, V.I. Berendyaev, A.F. Mironov, S.V. Novikov, A.V. Vannikov, 2006, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2006, Vol. 48, No. 2, pp. 254–262.

This work was supported by the Russian Foundation for Basic Research, project nos. 03-03-33067 and 05-03-33052; the International Science and Technology Center, project nos. 2207, 623-2, and 2461; the Federal Goal Scientific-Technical Program “Nanosystems Industry and Materials,” project no. IN. 13.1/001; and in part by the US National Science Promotion Foundation and the Civilian Research and Development Foundation, grant no. RE2-2524-MO-03.

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Mal’tsev, E.I., Brusentseva, M.A., Rumyantseva, V.D. et al. Electrophosphorescence of aromatic polyimides doped with platinum porphyrins. Polym. Sci. Ser. A 48, 146–152 (2006). https://doi.org/10.1134/S0965545X06020076

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  • DOI: https://doi.org/10.1134/S0965545X06020076

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