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Metal-Containing Granulated Yh Zeolites with Hierarchic Structure in Isophorone Aromatization

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Abstract

The physicochemical properties of a series of catalysts based on granulated Na-Yh zeolite with the hierarchic (micro–meso–macro) pore structure (Na-Yh, HNa-Yh, MgO/Na-Yh, La2O3/Na-Yh, TiO2/Na-Yh) and the activity and selectivity of these catalysts in isophorone aromatization were studied. MgO/Na-Yh and La2O3/Na-Yh zeolites with high content of basic sites and low content of Brønsted acid sites are the most effective in the synthesis of 3,5-dimethylphenol: The 3,5-dimethylphenol formation selectivity reaches 63–69% at 87–94% isophorone conversion. In the presence of Na-Yh zeolite containing both acid and base sites, the prevalent reactions are isophorone isomerization and synthesis of trimethylbenzenes. The modification of Na-Yh with titanium oxide leads to an increase in the content of acid sites on the TiO2/Na-Yh surface and to the prevalence of the aromatization to form trimethylbenzenes. In the presence of HNa-Yh containing a set of the strongest Brønsted and Lewis acid sites, isophorone transforms into a mixture of polymethylbenzenes.

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Funding

The study was financially supported by the Russian Science Foundation, project no. 23-13-00213.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, Ufa, 450075, Bashkortostan, Russia

    N. G. Grigor’eva, V. Yu. Kirsanov, A. N. Khazipova, S. V. Bubennov, V. R. Bikbaeva, D. V. Serebrennikov & B. I. Kutepov

  2. Institute of Petroleum Refining and Petrochemistry, Ufa, 450065, Bashkortostan, Russia

    V. Yu. Kirsanov, L. F. Korzhova & S. G. Karchevskii

Authors
  1. N. G. Grigor’eva
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  2. V. Yu. Kirsanov
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  3. L. F. Korzhova
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  4. S. G. Karchevskii
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  5. A. N. Khazipova
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  6. S. V. Bubennov
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  7. V. R. Bikbaeva
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  8. D. V. Serebrennikov
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  9. B. I. Kutepov
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Correspondence to N. G. Grigor’eva or V. Yu. Kirsanov.

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Grigor’eva, N.G., Kirsanov, V.Y., Korzhova, L.F. et al. Metal-Containing Granulated Yh Zeolites with Hierarchic Structure in Isophorone Aromatization. Pet. Chem. (2024). https://doi.org/10.1134/S0965544124020038

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