Skip to main content
SpringerLink
Log in

Hydrodecyclization of Naphthenes over Iridium-Containing Zeolite Catalysts

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

The study investigates the hydrodecyclization of decalin over zeolite catalysts. The synthesized catalysts were characterized using a combination of physicochemical methods, such as TEM, SEM, low-temperature nitrogen adsorption/desorption, and XPS. The zeolite structure was found to have a major effect on the hydrodecyclization process. This process involves the isomerization of one ring followed by the opening of that ring. Incorporating iridium into the catalysts promoted the production of branched hydrocarbons. When testing the process in the temperature range of 300–400°C and at an initial hydrogen pressure of 50 atm, the Ir/BEA catalyst exhibited the highest activity: at 350°C the decyclization of decalin exceeded 50%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1.
Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Yadav, V.G., Yadav, G.D., and Patankar, S.C., Clean Technol. Environ. Policy, 2020, vol. 22, pp. 1757–1774. https://doi.org/10.1007/s10098-020-01945-5

    Article  PubMed  PubMed Central  Google Scholar 

  2. Jampaiah, D., Murzin, D.Y., Lee, A.F., Schaller, D., Bhargava, S.K., Tabulo, B., and Wilson, K., Energy Environ. Sci., 2022, vol. 15, no. 5, pp. 1760–1804. https://doi.org/10.1039/D1EE02363B

    Article  CAS  Google Scholar 

  3. Naranov, E.R., Sadovnikov, A.A., Arapova, O.V., Bugaev, A.L., Usoltsev, O.A., Gorbunov, D.N., Russo, V., Murzin, D.U., and Maximov, A.L., Catal. Sci. Technol., 2023, vol. 13, no. 5, pp. 1571–1583. https://doi.org/10.1039/D2CY01127A

    Article  CAS  Google Scholar 

  4. Shirokopoyas, S.I., Baranova, S.V., Maksimov, A.L., Kardashev, S.V., Kulikov, A.B., Naranov, E.R., Vinokurov, V.A., Lysensko, S.V., and Karakhanov, E.A., Petrol. Chem., 2014, vol. 54, pp. 94–99. https://doi.org/10.1134/S0965544114020108

    Article  CAS  Google Scholar 

  5. Naranov, E., Sadovnikov, A., Arapova, O., Kuchinskaya, T., Usoltsev, O., Bugaev, A., Janssens, K., De Vos, D., and Maximov, A., Appl. Catal. B, 2023, vol. 334. https://doi.org/10.1016/j.apcatb.2023.122861

  6. Naranov, E.R., Sadovnikov, A.A., Bugaev, A.L., Shavaleev, D.A., and Maximov, A.L., Catal. Today, 2021, vol. 378, pp. 149–157. https://doi.org/10.1016/j.cattod.2021.06.011

    Article  CAS  Google Scholar 

  7. Naranov, E.R., Dement’ev, K.I., Gerzeliev, I.M., Kolesnichenko, N.V., Roldugina, E.A., and Maksimov, A.L., Petrol. Chem., 2019, vol. 59, pp. 247–261. https://doi.org/10.1134/S0965544119030101

    Article  CAS  Google Scholar 

  8. Naranov, E.R. and Maximov, A.L., Catal. Today, 2019, vol. 329, pp. 94–101. https://doi.org/10.1016/j.cattod.2018.10.068

    Article  CAS  Google Scholar 

  9. Golubev, O.V., Egazar’yants, S.V., Matevosyan, D.V., Naranov, E.R., Maksimov, A.L., and Karakhanov, E.A., Russ. J. Appl. Chem., 2018, vol. 91, pp. 2040–2045. https://doi.org/10.1134/S1070427218120169

    Article  CAS  Google Scholar 

  10. Pérot, G., Catal. Today, 2003, vol. 86, nos. 1–4, pp. 111–128. https://doi.org/10.1016/S0920-5861(03)00407-3

    Article  CAS  Google Scholar 

  11. Shimada, H., Yoshitomi, S., Sato, T., Matsubayashi, N., Imamura, M., Yoshimura, Y., and Nishijima, A., Stud. Surf. Sci. Catal., 1997, vol. 106, pp. 115–128. https://doi.org/10.1016/S0167-2991(97)80010-9

    Article  CAS  Google Scholar 

  12. Sundaramurthy, V., Eswaramoorthi, I., Dalai, A.K., and Adjaye, J., Micropor. Mesopor. Mater., 2008, vol. 111, nos. 1–3, pp. 560–568. https://doi.org/10.1016/j.micromeso.2007.08.037

    Article  CAS  Google Scholar 

  13. Dufresne, P., Appl. Catal. A: General, 2007, vol. 322, pp. 67–75. https://doi.org/10.1016/j.apcata.2007.01.013

    Article  CAS  Google Scholar 

  14. Aho, A., Roggan, S., Simakova, O.A., Salmi, T., and Murzin, D.Y. Catal. Today, 2015, vol. 241, pp. 195–199. https://doi.org/10.1016/j.cattod.2013.12.031

    Article  CAS  Google Scholar 

  15. Calemma, V., Giardino, R., and Ferrari, M., Fuel Process. Technol., 2010, vol. 91, no. 7, pp. 770–776. https://doi.org/10.1016/j.fuproc.2010.02.012

    Article  CAS  Google Scholar 

  16. Bjelić, A., Grilc, M., Huš, M., and Likozar, B., Chem. Eng. J., 2019, vol. 359, pp. 305–320. https://doi.org/10.1016/j.cej.2018.11.107

    Article  CAS  Google Scholar 

  17. He, T., Wang, Y., Miao, P., Li, J., Wu, J., and Fang, Y., Fuel, 2013, vol. 106, pp. 365–371. https://doi.org/10.1016/j.fuel.2012.12.025

    Article  CAS  Google Scholar 

  18. Weitkamp, J., ChemCatChem., 2012, vol. 4, no. 3, pp. 292–306. https://doi.org/10.1002/cctc.201100315

    Article  CAS  Google Scholar 

  19. Song, C., Catal. Today, 2003, vol. 86, pp. 211–263. https://doi.org/10.1016/S0920-5861(03)00412-7

    Article  CAS  Google Scholar 

  20. Topsøe, H., Clausen, B.S., and Massoth, F.E., Catalysis: Science and Technology, Springer Berlin, Heidelberg, 1996, pp. 1–269. https://doi.org/10.1007/978-3-642-61040-0_1

  21. Du, H., Fairbridge, C., Yang, H., and Ring, Z., Appl. Catal. A: General, 2005, vol. 294, pp. 1–21. https://doi.org/10.1016/j.apcata.2005.06.033

    Article  CAS  Google Scholar 

  22. Zhang, H., Meng, X., Li, Y., and Lin, Y.S., Ind. Eng. Chem. Res., 2007, vol. 46, pp. 4186–4192. https://doi.org/10.1021/ie061138e

    Article  CAS  Google Scholar 

  23. Fu, D., van der Heijden, O., Stanciakova, K., Schmidt, J.E., and Weckhuysen, B.M., Angew. Chem. Int. Ed., 2020, vol. 59, no. 36, pp. 15502–15506. https://doi.org/10.1002/anie.201916596

    Article  CAS  Google Scholar 

  24. Song, C. and Ma, X., Appl. Catal. B, 2003, vol. 41, nos. 1–2, pp. 207–238. https://doi.org/10.1016/S0926-3373(02)00212-6

    Article  CAS  Google Scholar 

  25. Escalona, G., Rai, A., Betancourt, P., and Sinha, A.K., Fuel, 2018, vol. 219, pp. 270–278. https://doi.org/10.1016/j.fuel.2018.01.134

    Article  CAS  Google Scholar 

  26. Santana, R., Do, P., Santikunaporn, M., Alvarez, W., Taylor, J., Sughrue, E., and Resasco, D., Fuel, 2006, vol. 85, nos. 5–6, pp. 643–656. https://doi.org/10.1016/j.fuel.2005.08.028

    Article  CAS  Google Scholar 

  27. Jacquin, M., Jones, D.J., Rozière, J., López, A.J., Rodríguez-Castellón, E.J., Trejo Menayo, J.M., Lenarda, M., Storaro, L., Vaccari, A., and Albertazzi, S.J., J. Catal., 2004, vol. 228, no. 2, pp. 447–459. https://doi.org/10.1016/j.jcat.2004.09.017

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

This work was performed using equipment of the Shared Research Center “Analytical center of deep oil processing and petrochemistry” of TIPS RAS. The authors thank the Joint Research Center for Physical Methods of Research at the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences (JRC PMR IGIC RAS) for their cooperation in the investigation of catalyst properties.

Funding

This study was funded by the Russian Science Foundation (project no. 22-79-10294).

Author information

Authors and Affiliations

  1. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    L. G. Mamian, A. A. Sadovnikov, O. V. Arapova, A. L. Maximov & E. R. Naranov

Authors
  1. L. G. Mamian
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Sadovnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. V. Arapova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. L. Maximov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. R. Naranov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. R. Naranov.

Ethics declarations

A.L. Maximov, a co-author, is the editor-in-chief at the Neftekhimiya (Petroleum Chemistry) Journal. The other co-authors declare no conflict of interest requiring disclosure in this article.

Additional information

Publisher's Note. Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mamian, L.G., Sadovnikov, A.A., Arapova, O.V. et al. Hydrodecyclization of Naphthenes over Iridium-Containing Zeolite Catalysts. Pet. Chem. 63, 1080–1086 (2023). https://doi.org/10.1134/S0965544123080054

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544123080054

Keywords:

Search

Navigation