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Fischer–Tropsch Synthesis over Bifunctional Catalysts Based on HBeta Zeolite

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Abstract

A number of catalysts were synthesized from a composite mixture consisting of a metal component (specifically, a Co–Al2O3/SiO2 catalyst in an amount of 20–40% for the synthesis of long-chain hydrocarbons), an acid component (Beta zeolite in the H-form, 20–50%), and a binder (boehmite). The catalysts were characterized by XRD, low-temperature argon adsorption/desorption, and TPR, and tested in Fischer–Tropsch synthesis at 2.0 MPa, 240°C, and GHSV 1000 h–1. The activity and selectivity of the catalysts were compared, and the composition of the synthetic products was investigated. The content of the zeolite component was found to be critical to the cracking and isomerization activity of the catalysts. It was further shown that the ratio between the active components correlates with the C5+ productivity and the selectivity towards fuel-range hydrocarbons. The catalysts with Co–Al2O3/SiO2 to HBeta ratios of 0.75 and 1.3 were found to be optimal for high-performance synthesis of gasoline-range (C5–C10) and diesel-range (C11–C18) hydrocarbons, respectively.

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REFERENCES

  1. Tomasek, S., Lónyi, F., Valyon, J., and Hancsók, J., Energy Convers. Manag., 2020, vol. 213, article 112775. https://doi.org/10.1016/j.enconman.2020.112775

  2. Martinelli, M., Gnanamani, M.K., Le Viness, S., Jacobs, G., and Shafer, W.D., Appl. Catal. A: General, 2020, vol. 608, article 117740. https://doi.org/10.1016/j.apcata.2020.117740

  3. van Steen, E., Claeys, M., Möller, K.P., Nabaho, D., Appl. Catal. A: General, 2018, vol. 549, pp. 51–59. https://doi.org/10.1016/j.apcata.2017.09.019

    Article  CAS  Google Scholar 

  4. Eliseev, O.L., Savost’yanov, A.P., Sulima, S.I., and Lapidus, A.L., Mendeleev Commun., 2018, vol. 28, pp. 345–351. https://doi.org/10.1016/j.mencom.2018.07.001

    Article  CAS  Google Scholar 

  5. Gholami, Z., Tišler, Z., and Rubáš, V., Catal. Rev., 2021, vol. 63, pp. 512–59. https://doi.org/10.1080/01614940.2020.1762367

    Article  CAS  Google Scholar 

  6. Khodakov, A.Y., Chu, W., and Fongarland, P., Chem. Rev., 2007, vol. 107, pp. 1692–1744. https://doi.org/10.1021/cr050972v

    Article  CAS  PubMed  Google Scholar 

  7. Vogel, A.P., van Dyk, B., and Saib, A.M., Catal. Today, 2016, vol. 259, pp. 323–330. https://doi.org/10.1016/j.cattod.2015.06.018

    Article  CAS  Google Scholar 

  8. Ma, W., Kang, J., Jacobs, G., and Hopps, S.D., Reactions, 2021, vol. 2, pp. 374–390. https://doi.org/10.3390/reactions2040024

    Article  Google Scholar 

  9. Kulikova, M.V., Catal. Today, 2020, vol. 348, pp. 89–94. https://doi.org/10.1016/j.cattod.2019.09.036

    Article  CAS  Google Scholar 

  10. Sulima, S.I., Bakun, V.G., Chistyakova, N.S., Larina, M.V., Yakovenko, R.E., and Savost’yanov, A.P., Petrol. Chem., 2021, vol. 61, no. 11, pp. 1178–1189. https://doi.org/10.1134/S0965544121110013

    Article  CAS  Google Scholar 

  11. Suo, Y., Yao, Y., Zhang, Y., Xing, S., and Yuan, Z., J. Indust. Eng. Chem., 2022, vol. 115, pp. 92–119. https://doi.org/10.1016/j.jiec.2022.08.026

    Article  CAS  Google Scholar 

  12. Iglesia, E., Appl. Catal. A: General, 1997, vol. 161, pp. 59–78. https://doi.org/10.1016/S0926-860X(97)00186-5

    Article  CAS  Google Scholar 

  13. Gupta, S., Fernandes, R., Patel, R., Spreitzer, M., and Patel, N., Appl. Catal. A: General, 2023, vol. 661, article 119254. https://doi.org/10.1016/j.apcata.2023.119254

  14. Glasser, D., Hildebrandt, D., Liu, X., Lu, X., and Masuku, C.M., Cur. Opin. Chem. Eng., 2012, vol. 1, pp. 296–302. https://doi.org/10.1016/j.coche.2012.02.001

    Article  CAS  Google Scholar 

  15. Li, X., Chen, Y., Liu, S., Zhao, N., Jiang, X., Su, M., and Li, Z., Chem. Eng. J., 2021, vol. 416. 129180. https://doi.org/10.1016/j.cej.2021.129180

  16. Deviana, D., Rhim, G.B., Kim, Y., Lee, H.S., Lee, G.W., Youn, M.H., Kim, K.Y., Koo, K.Y., Park, J., and Chun, D.H., Chem. Eng. J., 2023, vol. 455, no. 2, article 140646. https://doi.org/10.1016/j.cej.2022.140646

  17. Liu, C., Chen, Y., Zhao, Y., Lyu, S., Wei, L., Li, X., and Zhang, Y., Li, J., Fuel, 2020, vol. 263. 116619. https://doi.org/10.1016/j.fuel.2019.116619

  18. Espinosa, G., Domínguez, J.M., Morales-Pacheco, P., Tobon, A., Aguilar, M., and Benítez, J., Catal. Today, 2011, vol. 166, pp. 47–52. https://doi.org/10.1016/j.cattod.2011.01.025

    Article  CAS  Google Scholar 

  19. Sineva, L.V., Gorokhova, E.O., Gryaznov, K.O., Ermolaev, I.S., and Mordkovich, V.Z., Catal. Today, 2021, vol. 378, pp. 140–148. https://doi.org/10.1016/j.cattod.2021.02.018

    Article  CAS  Google Scholar 

  20. Asalieva, E.Y., Kul’chakovskaya, E.V., Sineva, L.V., and Mordkovich, V.Z., Petrol. Chem., 2020, vol. 60, pp. 69–74. https://doi.org/10.1134/S0965544120010028

    Article  CAS  Google Scholar 

  21. Yakovenko, R.E., Agliullin, M.R., Zubkov, I.N., Papeta, O.P., Khliyan, G.T., and Savost’yanov, A.P., Petrol. Chem., 2021, vol. 61, no. 3, pp. 378–387. https://doi.org/10.1134/S0965544121030063

    Article  CAS  Google Scholar 

  22. Yakovenko, R.E., Bakun, V.G., Agliullin, M.R., Sulima, S.I., Zubkov, I.N., Pyatikonova, V.V., Bozhenko, E.A., and Savost’yanov, A.P., Petrol. Chem., 2022, vol. 62, no. 8, pp. 950–961. https://doi.org/10.1134/S0965544122070209

    Article  CAS  Google Scholar 

  23. Gorokhova, E.O., Kul’chakovskaya, E.V., Asalieva, E.Yu., Gryaznov, K.O., Mitberg, E.B., Sineva, L.V., and Mordkovich, V.Z., Petrol. Chem., 2021, vol. 61, no. 3, pp. 357–363. https://doi.org/10.1134/S0965544121030208

    Article  CAS  Google Scholar 

  24. Prieto, G., Martínez, A., Concepción, P., and MorenoTost, R., J. Catal., 2009, vol. 266, pp. 129–144. https://doi.org/10.1016/j.jcat.2009.06.001

    Article  CAS  Google Scholar 

  25. Martínez, A., Rollán, J., Arribas, M.A., Cerqueira, H.S., and Costa, A.F., J. Catal., 2007, vol. 249, pp. 162–173. https://doi.org/10.1016/j.jcat.2007.04.012

    Article  CAS  Google Scholar 

  26. Flores, C.B., Ordomsky, V.V., Zholobenko, V.L., Baaziz, W.M., Nilson, R., and Khodakov, A.Y., ChemCatChem., 2018, vol. 10, no. 10, pp. 2291–2299. https://doi.org/10.1002/cctc.201701848

    Article  CAS  Google Scholar 

  27. Rodionova, L.I., Knyazeva, E.E., Ivanova, I.I., and Konnov, S.V., Petrol. Chem., 2019, vol. 59, no. 4, pp. 455–470. https://doi.org/10.1134/S0965544119040133

    Article  CAS  Google Scholar 

  28. Sineva, L.V., Khatkova, E.Y., Kriventseva, E.V., and Mordkovich, V.Z., Mendeleev Commun., 2014, vol. 24, no. 5, pp. 316–318. https://doi.org/10.1016/j.mencom.2014.09.024

    Article  CAS  Google Scholar 

  29. Li, H., Hou, B., Wang, J., Qin, C., Zhong, M., Huang, X., Jia, L., and Li, D., Mol. Catal., 2018, vol. 459, pp. 106–112. https://doi.org/10.1016/j.mcat.2018.08.002

    Article  CAS  Google Scholar 

  30. Yakovenko, R.E., Bakun, V.G., Zubkov, I.N., Papeta, O.P., Saliev, A.N., Agliullin, M.R., and Savost’yanov, A.P., Kinet. Catal., 2022, vol. 63, pp. 399–411. https://doi.org/10.1134/S0023158422040139

    Article  CAS  Google Scholar 

  31. Subramanian, V., Cheng, K., Lancelot, C., Heyte, S., Paul, S., Moldovan, S., Ersen, O., Marinova, M., Ordomsky, V.V., and Khodakov, A.Y., ACS Catal., 2016, vol. 6, pp. 1785– 1792. https://doi.org/10.1021/acscatal.5b01596

    Article  CAS  Google Scholar 

  32. Savost’yanov, A.P., Yakovenko, R.E., Narochnyi, G.B., Bakun, V.G., Sulima, S.I., Yakuba, E.S., and Mitchenko, S.A., Kinet. Catal., 2017, vol. 58, no. 1, pp. 81–91. https://doi.org/10.1134/S0023158417010062

    Article  CAS  Google Scholar 

  33. PDF-2. The powder diffraction file TM. International Center for Diffraction Data (ICDD). PDF-2 Release 2012. https://www.icdd.com/

  34. Young, R.A., The Rietveld Method, Oxford University Press, 1995.

  35. Schanke, D., Vada, S., Blekkan, E.A., Hilmen, A.M., Hoff, A., and Holmen, A., J. Catal., 1995, vol. 156, no. 1, pp. 85–95. https://doi.org/10.1006/jcat.1995.1234

    Article  CAS  Google Scholar 

  36. Xu, D., Li, W., Duan, H., Ge, Q., and Xu, H., Catal. Lett., 2005, vol. 102, no. 3, pp. 229–235. https://doi.org/10.1007/s10562-005-5861-7

    Article  CAS  Google Scholar 

  37. Sulima, S.I., Bakun, V.G., Yakovenko, R.E., Shabel’skaya, N.P., Saliev, A.N., Narochnyi, G.B., and Savost’yanov, A.P., Kinet. Catal., 2018, vol. 59, no. 2, pp. 218–228. https://doi.org/10.1134/S0023158418020131

    Article  CAS  Google Scholar 

  38. Wolf, M., Fischer, N., and Claeys, M., Chem. Catal., 2021, vol. 1, no. 5, pp. 1014–1041. https://doi.org/10.1016/j.checat.2021.08.002

    Article  CAS  Google Scholar 

  39. Bezemer, G.L., Radstake, P.B., Koot, V., van Dillen, A.J., Geus, J.W., and de Jong, K.P., J. Catal., 2006, vol. 237, pp. 291–302. https://doi.org/10.1016/j.jcat.2005.11.015

    Article  CAS  Google Scholar 

  40. Akhmedov, V.M. and Al-Khowaiter, S.H., Catal. Rev., 2007, vol. 49, p. 33–139. https://doi.org/10.1080/01614940601128427

    Article  CAS  Google Scholar 

  41. Khairullina, Z.R., Agliullin, M.R., Alekhina, I.E., and Kutepov, B.I., Vestn. Bashkir. Univ., 2020, vol. 25, pp. 495–505. https://doi.org/10.33184/bulletin-bsu-2020.3.6

    Article  Google Scholar 

  42. Savost’yanov, A.P., Yakovenko, R.E., Narochnyi, G.B., Zubkov, I.N., and Nepomnyashchikh, E.V., Petrol. Chem., 2020, vol. 60, no. 5, pp. 577–584. https://doi.org/10.1134/S0965544120050102

    Article  Google Scholar 

  43. Yakovenko, R.E., Savost’yanov, A.P., Narochniy, G.B., Soromotin, V.N., Zubkov, I.N., Papeta, O.P., Svetogorov, R.D., and Mitchenko, S.A., Catal. Sci. Technol., 2020, vol. 10, no. 22, pp. 7613–7629. https://doi.org/10.1039/D0CY00975J

    Article  CAS  Google Scholar 

  44. Chalupka, K.A., Casale, S., Zurawicz, E., Rynkowski, J., and Dzwigaj, S., Micropor. Mesopor. Mater., 2015, vol. 211, pp. 9–18. https://doi.org/10.1016/j.micromeso.2015.02.024

    Article  CAS  Google Scholar 

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Funding

This study was carried out with financial support from the Ministry of Sciences and Higher Education of the Russian Federation within State Assignment FENN-2020-0021 (project no. 2019-0990), using equipment of the Nanotechnology Center for Collective Use, South Russian State Polytechnic University.

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  1. Platov South Russian State Polytechnic University, 346428, Novocherkassk, Russia

    O. P. Papeta, S. I. Sulima, V. G. Bakun, I. N. Zubkov, A. N. Saliev & R. E. Yakovenko

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  1. O. P. Papeta
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Papeta, O.P., Sulima, S.I., Bakun, V.G. et al. Fischer–Tropsch Synthesis over Bifunctional Catalysts Based on HBeta Zeolite. Pet. Chem. 63, 737–745 (2023). https://doi.org/10.1134/S0965544123060063

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