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Influence of the Template/Al2O3 Ratio in Reaction Aluminophosphate Gels on the Characteristics of Intermediate Phases and AlPO4-11 Molecular Sieves

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Abstract

Crystallization of aluminophosphate gels prepared using boehmite and phosphoric acid with different di-n-propylamine/Al2O3 ratios was studied. Depending on the di-n-propylamine/Al2O3 ratio, the following intermediate phases can be formed in reaction gels in the course of further crystallization: hydrated aluminophosphate AlPO4·2H2O, the layered phase, and their mixtures. Procedures were suggested for controlling the morphology of the AlPO4-11 molecular sieve, based on variation of the template/Al2O3 ratio in the course of the reaction gel preparation.

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Funding

The study was supported by the Russian Science Foundation, project no. 23-73-00119, https://rscf.ru/project/23-73-00119/.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, Bashkortostan, 450075, Ufa, Russia

    M. R. Agliullin, R. Z. Kuvatova & B. I. Kutepov

  2. Ufa University of Science and Technologies, Bashkortostan, 450076, Ufa, Russia

    V. Yu. Gus’kov & V. V. Lazarev

Authors
  1. M. R. Agliullin
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  2. R. Z. Kuvatova
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  3. V. Yu. Gus’kov
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  4. V. V. Lazarev
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  5. B. I. Kutepov
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Correspondence to M. R. Agliullin.

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Agliullin, M.R., Kuvatova, R.Z., Gus’kov, V.Y. et al. Influence of the Template/Al2O3 Ratio in Reaction Aluminophosphate Gels on the Characteristics of Intermediate Phases and AlPO4-11 Molecular Sieves. Pet. Chem. 63, 708–717 (2023). https://doi.org/10.1134/S0965544123060026

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