Abstract
Incorporating a second metal into the monometallic bifunctional catalyst structure results in appearance of new catalytic characteristics and increase in the catalytic productivity. This type of catalyst is called bimetallic catalyst, which is better than a monometallic one in industrial processes, because it enhances some catalytic features like metal dispersion, activity, selectivity, stability, and lifespan. Different researches have asserted that the bimetallic catalyst increases the yield of the desired branched alkanes and decreases the undesired low-molecular-weight gaseous products. The enhancement of catalytic properties of the bimetallic catalyst is ascribed mainly to the electronic features and geometric structure of nanoparticles of two metals and increases the Lewis acidity and balance between metals and a supporter. In this paper, the theoretical and experimental fundamentals of bimetallic catalysis are reviewed based on many trusted experimental works of different researchers.
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REFERENCES
Webb, R., Increasing Gasoline Octane Levels to Reduce Vehicle Emissions: A Review of Federal and State Authority, Sabin Center for Climate Change Law, Columbia Law School, 2017.
Okuhara, T., J. Jpn. Petrol. Inst., 2004, vol. 47, no. 1, pp. 1–10. https://doi.org/10.1627/jpi.47.1
Treese, S.A., Jones, D.S., and Pujadó, P.R., Eds., Handbook of Petroleum Processing, Second Edition, Switzerland: Springer, 2015. https://doi.org/10.1007/978-3-319-05545-9
Ghosh, P., Hickey, K.J., and Jaffe, S.B., Ind. Eng. Chem. Res., 2006, vol. 45, no. 1, pp. 337–345. https://doi.org/10.1021/ie050811h
Ono, Y., Catal. Today, 2003, vol. 81, no. 1, pp. 3–16. https://doi.org/10.1016/S0920-5861(03)00097-X
Degnan, T.F., Topics Catal., 2000, vol. 13, no. 4, pp. 349–356. https://doi.org/10.1023/A:1009054905137
Tanabe, K. and Hölderich, W.F., Appl. Catal. A: Gen., 1999, vol. 181, no. 2, pp. 399–434. https://doi.org/10.1016/S0926-860X(98)00397-4
Weitkamp, J., Solid State Ionics, 2000, vol. 131, nos. 1–2, pp. 175–188. https://doi.org/10.1016/S0167-2738(00)00632-9
AlKhafaji, K.S., Al-Zaidi, B.Y., Shakor, Z.M., and Hussein, S.J., J. Petrol. Res. Studies, 2022, vol. 12, no. 2, pp. 64‒80. https://doi.org/10.52716/jprs.v12i2.658
Sinfelt, J.H., Acc. Chem. Res., 1987, vol. 20, no. 4, pp. 134–139. https://doi.org/10.1021/ar00136a002
Coker, A.K., Petroleum Refining Design and Applications Handbook, vol. 1, John Wiley & Sons, 2018. https://doi.org/10.1002/9781119257110
Hancsók, J., Holló, A., Debreczeni, É., Perger, J., and Kalló, D., Stud. Surf. Sci. Catal., 1999, vol. 125, pp. 417–424. https://doi.org/10.1016/s0167-2991(99)80241-9
Khalaf, Y.H., Sherhan, B.Y., and Zaidoon, M., Eng. Technol. J., 2022, vol. 40, no. 9, pp. 1158–1170. https://doi.org/10.30684/etj.2022.132491.1124
Bergvall, C. and Westerholm, R., Atmos. Environ., 2009, vol. 43, no. 25, pp. 3883–3890. https://doi.org/10.1016/j.atmosenv.2009.04.055
Tanner, R.L., Miguel, A.H., De Andrade, J.B., Gaffney, J.S., and Streit, G.E., Environ. Sci. Technol., 1988, vol. 22, no. 9, pp. 1026–1034. https://doi.org/10.1021/es00174a005
Niwa, M., Katada, N., and Okumura, K., Characterization and Design of Zeolite Catalysts, Berlin: Springer, 2010. https://doi.org/10.1007/978-3-642-12620-8
de Jong, K.P., Ed. Synthesis of Solid Catalysts, Weinheim: Wiley-VCH Verlag GmbH & Co. KGaA, 2009. https://doi.org/10.1002/9783527626854
Mowery, D.L., and McCormick, R.L., Appl. Catal. B: Environ., 2001, vol. 34, no. 4, pp. 287–297. https://doi.org/10.1016/S0926-3373(01)00222-3
Lamberov, A.A., Mukhambetov, I.N., and Zalyaliev, R.F., Catal. Ind., 2014, vol. 6, no. 2, pp. 128–133. https://doi.org/10.1134/S2070050414020068
Sachtler, W.M. and Zhang, Z., Adv. Catal., 1993, vol. 39, pp. 129–220. https://doi.org/10.1016/S0360-0564(08)60578-7
Kikuchi, E., Tsurumi, M., Kimura, T., and Morita, Y., Bull. Jpn. Petrol. Inst., 1973, vol. 15, no. 2, pp. 122–128. https://doi.org/10.1627/jpi1959.15.122
Structure and Reactivity of Metals in Zeolite Materials, Pariente, M.S.-S. and Sánchez-Sánchez, M., Eds., Switzerland: Springer, 2018. https://doi.org/10.1007/978-3-319-98905-1
Saberi, M.A., Le Van Mao, R., Martin, M., and Mak, A.W.H., Appl. Catal. A: Gen., 2001, vol. 214, no. 2, pp. 229–236. https://doi.org/10.1016/S0926-860X(01)00493-8
Scherzer, J. and Gruia, A.J., Hydrocracking Science and Technology, CRC Press, 1996. https://doi.org/10.1201/9781482233889
Weisz, P.B., Adv. Catal., 1962, vol. 13, pp. 137–190. https://doi.org/10.1016/S0360-0564(08)60287-4
Mills, G.A., Heinemann, H., Milliken, T.H., and Oblad, A.G., Ind. Eng. Chem., 1953, vol. 45, no. 1, pp. 134–137. https://doi.org/10.1021/ie50517a043
Sinfelt, J.H., Hurwitz, H., and Rohrer, J.C., J. Catal., 1962, vol. 1, no. 5, pp. 481–483. https://doi.org/10.1016/0021-9517(62)90097-0
Jiménez, C., Romero, F.J., Roldán, R., Marinas, J.M., and Gómez, J.P., Appl. Catal. A: Gen., 2003, vol. 249, no. 1, pp. 175–185. https://doi.org/10.1016/S0926-860X(03)00177-7
Kulprathipanja, S., Zeolites in Industrial Separation and Catalysis, Weinheim: WILEY-VCH Verlag, GmbH & Co. KGaA, 2010. ISBN: 978-527-32505-4
Demirci, Ü.B. and Garin, F., Catal. Lett., 2001, vol. 76, no. 1, pp. 45–51. https://doi.org/10.1023/A:1016707621813
Zhou, J., Zhao, J., Zhang, J., Zhang, T., Ye, M., and Liu, Z., Chinese J. Catal., 2020, vol. 41, no. 7, pp. 1048–1061. https://doi.org/10.1016/S1872-2067(20)63552-5
Zhao, J., Huffman, G.P., and Davis, B.H., Catal. Lett., 1994, vol. 24, no. 3, pp. 385–389. https://doi.org/10.1007/BF00811811
Gates, B.C., Flytzani-Stephanopoulos, M., Dixon, D.A., and Katz, A., Catal. Sci. Technol., 2017, vol. 7, no. 19, pp. 4259–4275. https://doi.org/10.1039/C7CY00881C
Moliner, M. and Corma, A., Microporous Mesoporous Mater., 2014, vol. 189, pp. 31–40. https://doi.org/10.1016/j.micromeso.2013.08.003
Liu, J., ACS Catal., 2017, vol. 7, no. 1, pp. 34–59. https://doi.org/10.1021/acscatal.6b01534
Yang, M., Liu, J., Lee, S., Zugic, B., Huang, J., Allard, L.F., and Flytzani-Stephanopoulos, M., J. Am. Chem. Soc., 2015, vol. 137, no. 10, pp. 3470–3473. https://doi.org/10.1021/ja513292k
Guczi, L. and Kiricsi, I., Appl. Catal. A: Gen., 1999, vol. 186, nos. 1–2, pp. 375–394. https://doi.org/10.1016/S0926-860X(99)00156-8
Li, X. and Iglesia, E., Chem. Commun., 2008, no. 5, pp. 594–596. https://doi.org/10.1039/B715543C
Guzman, J. and Gates, B.C., Dalton Trans., 2003, no. 17, pp. 3303–3318. https://doi.org/10.1039/B303285J
Corma, A., Nemeth, L.T., Renz, M., and Valencia, S., Nature, 2001, vol. 412, no. 6845, pp. 423–425. https://doi.org/10.1038/35086546
Corma, A., Llabres i Xamena, F.X., Prestipino, C., Renz, M., and Valencia, S., J. Phys. Chem. C, 2009, vol. 113, no. 26, pp. 11306–11315. https://doi.org/10.1021/jp902375n
Zhu, Y., Chuah, G., and Jaenicke, S., J. Catal., 2004, vol. 227, no. 1, pp. 1–10. https://doi.org/10.1016/j.jcat.2004.05.037
Lewis, J.D., Van de Vyver, S., and Román-Leshkov, Y., Angew. Chem., 2015, vol. 127, no. 34, pp. 9973–9976. https://doi.org/10.1002/ange.201502939
Corma, A., Iborra, S., and Velty, A., Chem. Rev., 2007, vol. 107, no. 6, pp. 2411–2502. https://doi.org/10.1021/cr050989d
Román-Leshkov, Y. and Davis, M.E., ACS Catal., 2011, vol. 1, no. 11, pp. 1566–1580. https://doi.org/10.1021/cs200411d
Moliner, M., Dalton Trans., 2014, vol. 43, no. 11, pp. 4197–4208. https://doi.org/10.1039/C3DT52293H
Luo, H.Y., Lewis, J.D., and Román-Leshkov, Y., Annu. Rev. Chem. Biomol. Eng., 2016, vol. 7, pp. 663–692. https://doi.org/10.1146/annurev-chembioeng-080615-034551
Yan, G.X., Wang, A., Wachs, I.E., and Baltrusaitis, J., Appl. Catal. A: Gen., 2019, vol. 572, pp. 210–225. https://doi.org/10.1016/j.apcata.2018.12.012
Li, H., Wang, J., Zhou, D., Tian, D., Shi, C., Mueller, U., Feyen, M., Gies, H., Xiao, F.-S., de Vos, D.E., Yokoi, T., Bao, X., and Zhang, W., Microporous Mesoporous Mater., 2015, vol. 218, pp. 160–166. https://doi.org/10.1016/j.micromeso.2015.07.020
Blomsma, E., Martens, J.A., and Jacobs, P.A., J. Catal., 1997, vol. 165, no. 2, pp. 241–248. https://doi.org/10.1006/jcat.1997.1473
Yang, G., Zhou, L., and Han, X., J. Mol. Catal. A: Chem., 2012, vol. 363, pp. 371–379. https://doi.org/10.1016/j.molcata.2012.07.013
Foger, K. and Anderson, J.R., J. Catal., 1980, vol. 145, no. 1, pp. 140–145.
Schwank, J., Gold Bull., 1985, vol. 18, no. 1, pp. 2–10. https://doi.org/10.1007/BF03214680
O’Cinneide, A. and Gault, F.G., J. Catal., 1975, vol. 37, no. 2, pp. 311–323. https://doi.org/10.1016/0021-9517(75)90165-7
Ciapetta, F.G. and Wallace, D.N., Catal. Rev., 1972, vol. 5, no. 1, pp. 67–158. https://doi.org/10.1080/01614947208076866
Sinfelt, J.H., J. Catal., 1973, vol. 29, no. 2, pp. 308–315. https://doi.org/10.1016/0021-9517(73)90234-0
Schwank, J., Gold Bulletin, 1983, vol. 16, no. 4, pp. 103–110.
Jarvis, J., He, P., Wang, A., and Song, H., Fuel, 2019, vol. 236, pp. 1301–1310. https://doi.org/10.1016/j.fuel.2018.09.109
Ahn, D.H., Lee, J.S., Nomura, M., Sachtler, W.M.H., Moretti, G., Woo, S.I., and Ryoo, R., J. Catal., 1992, vol. 133, no. 1, pp. 191–201. https://doi.org/10.1016/0021-9517(92)90197-P
Eswaramoorthi, I. and Lingappan, N., Appl. Catal. A: Gen., 2003, vol. 245, no. 1, pp. 119–135. https://doi.org/10.1016/S0926-860X(02)00637-3
Pope, T.D., Kriz, J.F., Stanciulescu, M., and Monnier, J., Appl. Catal. A: Gen., 2002, vol. 233, nos. 1–2, pp. 45–62. https://doi.org/10.1016/S0926-860X(02)00114-X
Fúnez, A., De Lucas, A., Sánchez, P., Ramos, M.J., and Valverde, J.L., Chem. Eng. J., 2008, vol. 136, nos. 2–3, pp. 267–275. https://doi.org/10.1016/j.cej.2007.03.062
Shi, G., Fang, D., and Shen, J., Microporous Mesoporous Mater., 2009, vol. 120, no. 3, pp. 339–345. https://doi.org/10.1016/j.micromeso.2008.11.022
Liu, P., Yao, Y., Zhang, X., and Wang, J., Chin. J. Chem. Eng., 2011, vol. 19, no. 2, pp. 278–284. https://doi.org/10.1016/S1004-9541(11)60166-3
Yue, C., Zhu, X., Rigutto, M., and Hensen, E., Appl. Catal. B: Environ., 2015, vol. 163, pp. 370–381. https://doi.org/10.1016/j.apcatb.2014.08.008
Wang, H., Ruan, H., Feng, M., Qin, Y., Job, H., Luo, L., Wang, C., Engelhard, M.H., and Yang, B., ChemSusChem, 2017, vol. 10, no. 8, pp. 1846–1856. https://doi.org/10.1002/cssc.201700160
Wang, J., Zhang, W., Suo, Y., and Wang, Y., J. Porous Mater., 2018, vol. 25, no. 5, pp. 1317–1324. https://doi.org/10.1007/s10934-017-0542-7
Karakoulia, S.A., Heracleous, E., and Lappas, A.A., Catal. Today, 2020, vol. 355, pp. 746–756. https://doi.org/10.1016/j.cattod.2019.04.072
Jarvis, J.S., Harrhy, J.H., He, P., Wang, A., Liu, L., and Song, H., Chem. Commun., 2019, vol. 55, no. 23, pp. 3355–3358. https://doi.org/10.1039/c9cc00338j
Lin, C., Pan, H., Yang, Z., Han, X., Tian, P., Li, P., Xiao, Z., Xu, J., and Han, Y.F., Ind. Eng. Chem. Res., 2020, vol. 59, no. 14, pp. 6424–6434. https://doi.org/10.1021/acs.iecr.9b05953
Oseke, G.G., Atta, A.Y., Mukhtar, B., El-Yakubu, B.J., and Aderemi, B.O., J. King Saud Univ. Eng. Sci., 2021, vol. 33, no. 8, pp. 531–538. https://doi.org/10.1016/j.jksues.2020.07.014
Yang, L., Song, Z., Yu, Y., Zhu, L., and Xia, D., Catal. Surv. Asia, 2020, vol. 24, no. 2, pp. 104–114. https://doi.org/10.1007/s10563-020-09295-4
Wang, S., Cao, M., Sun, S., Jiang, H., Duan, Y., Kong, X., and Wang, H., Fuel, 2020, vol. 280, p. 118274. https://doi.org/10.1016/j.fuel.2020.118274
Wang, D., Kang, X., Gu, Y., Zhang, H., Liu, J., Wu, A., Yan, H., Nian, C., and Fu, H., ACS Catal., 2020, vol. 10, no. 18, pp. 10449–10458. https://doi.org/10.1021/acscatal.0c01159
Xiao, Y., Shang, J., Zhai, M., and Qiao, C., Int. J. Energy Res., 2021, vol. 45, no. 6, pp. 9648–9656. https://doi.org/10.1002/er.6391
Hamied, R.S., Raouf, S.R., and Sukkar, K.A., Eng. Technol. J., 2013, vol. 31, no. 18, pp. 14‒35.
Sukkar, K.A., Raouf, S.R., and Hamied, R.S., Eng. Technol. J., 2013, vol. 31, no. 12, pp. 2357‒2380. https://doi.org/10.30684/etj.31.12A.12
Al-Karim, A.A., Shakor, Z.M., Al-Sheikh, F., and Anderson, W.A., Reac. Kinet., Mech. Cat., 2022, vol. 135, no. 2, pp. 847‒865. https://doi.org/10.1007/s11144-022-02179-w
Hamied, R.S. and Raouf, S.R., Iraqi J. Oil Res., 2022, vol. 2, no. 1, pp. 108–121. https://doi.org/10.55699/ijogr.2022.0201.1020
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Authors thank the Department of Chemical Engineering, University of Technology, Baghdad, Iraq for the support in the preparation of this review.
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Khalaf, Y.H., Sherhan, B.Y., Shakor, Z.M. et al. Bimetallic Catalysts for Isomerization of Alkanes (A Review). Pet. Chem. 63, 829–843 (2023). https://doi.org/10.1134/S0965544123050079
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DOI: https://doi.org/10.1134/S0965544123050079