Abstract
A number of bifunctional composite cobalt-based catalysts were prepared with various types of molecular sieves in the H-form (zeolites ZSM-5, Y, Beta, and Mordernite, and silicoaluminophosphate SAPO-11) as an acid component. The catalytic performance of these catalysts was comparatively assessed in integrated Fischer-Tropsch synthesis of fuels. The catalysts were found to exhibit high activity and high C5+ selectivity at 2.0 MPa, 240–250°C, and a gas hourly space velocity (WHSV) of 1000 h–1. With the CO conversion reaching 80.9–93.7%, the productivity was in the range of 146.4 kg/(m3cat h). The study further revealed the effects of the crystalline and porous structures of the molecular sieves on the hydrocarbon and fractional compositions of the fuel products and on the selectivity towards branched hydrocarbons. It was shown that catalysts based on HZSM-5 and HBeta zeolites are preferable for high-performance and selective synthesis of fuels. In the presence of the HZSM-5-based catalyst, an effect atypical of Fischer–Tropsch synthesis was observed for the first time: an elevation of the process temperature leads to an enhancement of C5+ selectivity.
Similar content being viewed by others
REFERENCES
Wang, C., Fang, W., Wang, L., and Xiao, F.S., J. Energy Chem., 2021, vol. 54, pp. 429–433. https://doi.org/10.1016/j.jechem.2020.06.006
Escorihuela, S., Toldra-Reig, F., Escolástico, S., Murciano, R., Martínez, A., Serra, J.M., J. Membr. Sci., 2021, vol. 619, p. 118516. https://doi.org/10.1016/j.memsci.2020.118516
Sulima, S.I., Bakun, V.G., Chistyakova, N.S., Larina, M.V., Yakovenko, R.E., Savost’yanov, A.P., Petrol. Chem., 2021, vol. 61, no. 11, pp. 1178–1189. https://doi.org/10.1134/S0965544121110013
Pedrolo, D.R.S., Ordomsky, V.V., Schwaab, M., Marcilio, N.R., and Khodakov, A.Y., J. Mater. Sci., 2021, vol. 56, pp. 18019–18030. https://doi.org/10.1007/s10853-021-06457-1
Guo, L., Sun, S., Li, J., Gao, W., Zhao, H., Zhang, B., He, Y., Zhang, P., Yang, G., and Tsubaki, N., Fuel, 2021, vol. 306, p. 121684. https://doi.org/10.1016/j.fuel.2021.121684
Sartipi, S., Makkee, M., Kapteijn, F., and Gascon, J., Catal. Sci. Technol., 2014, vol. 4, pp. 893–907. https://doi.org/10.1039/C3CY01021J
Chen, Y., Zhang, J., Jiang, X., Wei, L., Li, Z., and Liu, C., J. Taiwan Inst. Chem. Eng., 2020, vol. 116, pp. 153–159. https://doi.org/10.1016/j.jtice.2020.11.007
Yakovenko, R.E., Zubkov, I.N., Bakun, V.G., and Savostyanov, A.P., Petrol. Chem., 2021, vol. 61, no. 4, pp. 516–526. https://doi.org/10.1134/S096554412105008X
Khodakov, A.Y., Chu, W., and Fongarland, P., Chem. Rev., 2007, vol. 107, pp. 1692–1744. https://doi.org/10.1021/cr050972v
Sartipi, S., Parashar, K., Valero-Romero, M.J., Santos, V.P., van der Linden, B., Makkee, M., Kapteijn, F., and Gascon, J., J. Catal., 2013, vol. 305, pp. 179–190. https://doi.org/10.1016/j.jcat.2013.05.012
Savost’yanov, A.P., Yakovenko, R.E., Narochnyi, G.B., Zubkov, I.N., Sulima, S.I., Soromotin, V.N., Mitchenko, S.A., Petrol. Chem., 2020, vol. 60, no. 1, pp. 81–91. https://doi.org/10.1134/S0965544120010120
Eliseev, O.L., Savost’yanov, A.P., Sulima, S.I., and Lapidus, A.L., Mendeleev Commun., 2018, vol. 28, no. 4, pp. 345–351. https://doi.org/10.1016/j.mencom.2018.07.001
Wang, Y., Gao, W., Kazumi, S., Fang, Y., Shi, L., Yoneyama, Y., Yang, G., and Tsubaki, N., Fuel, 2019, vol. 253, pp. 249–256. https://doi.org/10.1016/j.fuel.2019.05.022
Weber, J.L., Martínez del Monte, D., Beerthuis, R., Dufour, J., Martos, C., de Jong, K.P., and de Jongh, P.E., Catal. Today, 2021, vol. 369, pp. 175–183. https://doi.org/10.1016/j.cattod.2020.05.016
Xing, C., Li, M., Zhang, G., Noreen, A., Fu, Y., Yao, M., Lu, C., Gao, X., Yang, R., and Amoo, C.C., Fuel, 2021, vol. 285, pp. 119233. https://doi.org/10.1016/j.fuel.2020.119233
Lu, P., Sun, J., Zhu, P., Abe, T., Yang, R., Taguchi, A., Vitidsant, T., and Tsubaki, N., J. Energy Chem., 2015, vol. 24, pp. 637–641. https://doi.org/10.1016/j.jechem.2015.08.004
Martínez del Monte, D., Vizcaíno, A.J., Dufour, J., and Martos, C., Int. J. Energy Res., 2021, vol. 46, pp. 5280–5287. https://doi.org/10.1002/er.7460
Sadek, R., Chalupka, K.A., Mierczynski, P., Rynkowski, J., Millot, Y., Valentin, L., Casale, S., and Dzwigaj, S., Catal. Today, 2020, vol. 354, pp. 109–122. https://doi.org/10.1016/j.cattod.2019.05.004
Xing, C., Yang, G., Wu, M., Yang, R., Tan, L., Zhu, P., Wei, Q., Li, J., Mao, J., Yoneyama, Y., and Tsubaki, N., Fuel, 2015, vol. 148, pp. 48-57. https://doi.org/10.1016/j.fuel.2015.01.040
Zhang, M., He, Z., Zhang, M., Wang, L., Wang, Q., Zhang, X., and Li, G., Fuel, 2022, vol. 316, p. 123166. https://doi.org/10.1016/j.fuel.2022.123166
Park, G., Ahn, C., Park, S., Lee, Y., Kwak, G., and Kim, S.K., Appl. Catal. A: Gen., 2020, vol. 607, p. 117840. https://doi.org/10.1016/j.apcata.2020.117840
Chalupka, K.A., Sadek, R., Szkudlarek, L., Mierczynski, P., Maniukiewicz, W., Rynkowski, J., Gurgul, J., Casale, S., Brouri, D., and Dzwigaj, S., Res. Chem. Intermed., 2021, vol. 47, pp. 397–418. https://doi.org/10.1007/s11164-020-04343-0
Yao, M., Yao, N., Liu, B., Li, S., Xu, L., and Li, X., Catal. Sci. Technol., 2015, vol. 5, pp. 2821–2828. https://doi.org/10.1039/C5CY00017C
Kang, J., Wang, X., Peng, X., Yang, Y., Cheng, K., Zhang, Q., and Wang, Y., Ind. Eng. Chem. Res., 2016, vol. 55, pp. 13008–13019. https://doi.org/10.1021/acs.iecr.6b03810
Sartipi, S., Makkee, M., Kapteijn, F., and Gascon, J., Catal. Sci. Technol., 2014, vol. 4, pp. 893–907. https://doi.org/10.1039/C3CY01021J
Kriventseva, E.V., Gryaznov, K.O., Khat’kova, E.Yu., Sineva, L.V., and Mordkovich, V.Z., Vestn. MITKhT im. M.V. Lomonosova, 2013, vol. 8, no. 6, pp. 9–16.
Sineva, L.V., Asalieva, E.Y., and Mordkovich, V.Z., Russ. Chem. Rev., 2015, vol. 84, p. 1176. https://doi.org/10.1070/RCR4464
Adeleke, A.A., Liu, X., Lu, X., Moyo, M., and Hildebrandt, D., Rev. Chem. Eng., 2020, vol. 36, no. 4, pp. 437–457. https://doi.org/10.1515/revce-2018-0012
Savost’yanov, A.P., Narochnyi, G.B., Yakovenko, R.E., Saliev, A.N., Sulima, S.I., Zubkov, I.N., Nekroenko, S.V., and Mitchenko, S.A., Petrol. Chem., 2017, vol. 57, pp. 1186–1189. https://doi.org/10.1134/S0965544117060251
Yakovenko, R.E., Zubkov, I.N., Bakun, V.G., Agliullin, M.R., Saliev, A.N., and Savost’yanov, A.P., Catal. Ind., 2021, vol. 13, pp. 230–238. https://doi.org/10.1134/S2070050421030120
Yakovenko, R.E., Savost’yanov, A.P., Narochniy, G.B., Soromotin, V.N., Zubkov, I.N., Papeta, O.P., Mit-chenko, S.A., and Svetogorov, R.D., Catal. Sci. Technol., 2020, vol. 10, no. 22, pp. 7613–7629. https://doi.org/10.1039/D0CY00975J
Sulima, S.I., Bakun, V.G., Yakovenko, R.E. Shabel’skaya, N.P., Saliev, A.N., Narochnyi, G.B., and Savost’yanov, A.P., Kinet. Catal., 2018, vol. 59, pp. 218–228 https://doi.org/10.1134/S0023158418020131
Akhmedov, V.M. and Al-Khowaiter, S.H., Cat. Rev.-Sci. Eng., 2007, vol. 49, no. 1, pp. 33–139. https://doi.org/10.1080/01614940601128427
PDF-2. The powder diffraction file TM. International Center for Diffraction Data (ICDD), 2014. https://www.icdd.com/
Young, R.A., The Rietveld Method, Oxford University Press, 1995, p. 298.
Schanke, D., Vada, S., Blekkan, E.A., Hilmen, A.M., Hoff, A., and Holmen, A., J. Catal., 1995, vol. 156, no. 1, pp. 85–95. https://doi.org/10.1006/jcat.1995.1234
Xu, D., Li, W., Duan, H., Ge, Q., and Xu, H., Catal. Lett., 2005, vol. 102, nos. 3–4, pp. 229–235. https://doi.org/10.1007/s10562-005-5861-7
Agliullin, M.R., Kutepov, B.I., Ostroumova, V.A., and Maximov, A.L., Petrol. Chem., 2021, vol. 61, no. 8, pp. 836–851. https://doi.org/10.1134/S096554412108003X
Okoye-Chine, C.G., Moyo, M., and Hildebrandt, D., Fuel, 2021, vol. 296, pp. 120667. https://doi.org/10.1016/j.fuel.2021.120667
van Steen, E., Sewell, G.S., Makhothe, R.A., Micklethwaite, C., Manstein, H., de Lange, M., and O’Connor, C.T., J. Catal., 1996, vol. 162, pp. 220–229. https://doi.org/10.1006/jcat.1996.0279
Lualdi, M., Lögdberg, S., Regali, F., Boutonnet, M., and Järås, S., Top. Catal., 2011, vol. 54, pp. 977–985. https://doi.org/10.1007/s11244-011-9719-5
Gnanamani, M.K., Shafer, W.D., Sparks, D.E., and Davis, B.H., Catal. Commun., 2011, vol. 12, pp. 936–939. https://doi.org/10.1016/j.catcom.2011.03.002
Yang, J., Ma, W., Chen, D., Holmen, A., and Davis, B.H., Appl. Catal. A: Gen., 2014, vol. 470, pp. 250–260. https://doi.org/10.1016/j.apcata.2013.10.061
Lögdberg, S., Yang, J., Lualdi, M., Walmsley, J.C., Järås, S., Boutonnet, M., Blekkan, E., Rytter, E., and Holmen, A., J. Catal., 2017, vol. 352, pp. 515–531.
Dry, M.E., Catal. Today, 2002, vol. 71, nos. 3–4, pp. 227–241. https://doi.org/10.1016/S0920-5861(01)00453-9
Pavlov, M.L. Basimova, R.A., Alyab’ev, A.S., and Makeeva, E.A., Neftegaz. Delo, 2012, vol. 10, no. 1, pp. 169–173.
Jin, Y., Li, Y., Zhao, S., Lv, Z., Wang, Q., Liu, X., and Wang, L., Micropor. Mesopor. Mater., 2012, vol. 147, no. 1, pp. 259–266. https://doi.org/10.1016/j.micromeso.2011.06.023
Cejka, J., Corma, A., and Zones, S., Zeolites and Catalysis: Synthesis Reactions and Applications; Weinheim: Wiley–VCH Verlag, GmbH & Co, 2010, p. 881.
Khairullina, Z.R., Agliullin, M.R., Alekhina, I.E., and Kutepov, B.I., Vestn. Bashkir. Univ., 2020, vol. 25, pp. 495–505. https://doi.org/10.33184/bulletin-bsu-2020.3.6
Weitkamp, J., Solid State Ionics, 2000, vol. 131, pp. 175–188. https://doi.org/10.1016/S0167-2738(00)00632-9
Martínez, A., Rollán, J., Arribas, M.A., Cerqueira, H.S., Costa, A.F., and Aguiar, E.F.S., J. Catal., 2007, vol. 249, pp. 162–173. https://doi.org/10.1016/j.jcat.2007.04.012
Funding
This study was carried out with financial support from the Ministry of Sciences and Higher Education of the Russian Federation within the state assignment (project no. 2019-0990), using equipment of the Nanotechnology Center for Collective Use, South Russian State Polytechnic University.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare no conflict of interest requiring disclosure in this article.
Rights and permissions
About this article
Cite this article
Yakovenko, R.E., Bakun, V.G., Agliullin, M.R. et al. Effects of Zeolite Type on Integrated Fischer–Tropsch Synthesis and Hydroprocessing. Pet. Chem. 62, 950–961 (2022). https://doi.org/10.1134/S0965544122070209
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0965544122070209