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Epoxidation of Allyl Chloride in the Presence of Tungsten Oxo–Peroxo Heteropoly Compounds of P(V), As(V), and Si(IV) Under Phase-Transfer Catalysis Conditions

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Abstract

This study investigates the behavior of nonmetals in tungsten oxo–peroxo heteropoly compounds in the reaction of allyl chloride epoxidation. The catalytic efficiency in epoxidation was shown to increase in the following order: Si(IV) < As(V) < P(V). Synergism in allyl chloride epoxidation was demonstrated for the first time for mixtures of tungsten oxo–peroxo heteropoly compounds of P and As, as well as P and Si. It was also shown that mixtures consisting of 70% P + 30% Si and 75% P + 25% As exhibit the highest catalytic activity. Finally, the article suggests a mechanism for the synergistic effect.

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Authors and Affiliations

  1. Tyumen State University, 625003, Tyumen, Russia

    L. P. Panicheva, G. P. Meteleva & S. A. Panichev

  2. Industrial University of Tyumen, 625000, Tyumen, Russia

    O. V. Ageikina

Authors
  1. L. P. Panicheva
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  2. G. P. Meteleva
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  3. O. V. Ageikina
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  4. S. A. Panichev
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Corresponding authors

Correspondence to G. P. Meteleva or O. V. Ageikina.

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Additional information

Translated from Neftekhimiya, 2021, Vol. 61, No. 6, pp. 869–874 https://doi.org/10.31857/S0028242121060125.

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Panicheva, L.P., Meteleva, G.P., Ageikina, O.V. et al. Epoxidation of Allyl Chloride in the Presence of Tungsten Oxo–Peroxo Heteropoly Compounds of P(V), As(V), and Si(IV) Under Phase-Transfer Catalysis Conditions. Pet. Chem. 61, 1270–1274 (2021). https://doi.org/10.1134/S0965544121110050

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