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Mathematical Modeling and Calculation of the Methanol Production Process via Carbon Dioxide Hydrogenation

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Abstract

This work is devoted to the mathematical modeling and calculation of the hydrogenation reaction of carbon dioxide to produce methanol using kinetic models developed with taking into account different understandings of the reaction mechanism; in particular, the Graaf and Rozovskii–Lin mechanisms are considered. It has been shown that under flow conditions, both models designed for describing the reaction of methanol production from synthesis gas fairly accurately describe the CO2 hydrogenation reaction. Under recycle flow conditions, a more accurate description of the product yield with changes in pressure and temperature can be obtained using a model based on the Graaff mechanism.

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Funding

The work was supported by the Russian Science Foundation, grant no. 17-73-30046.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    M. V. Magomedova, A. V. Starozhitskaya, M. I. Afokin, M. A. Kipnis & G. I. Lin

  2. Gubkin Russian State University of Oil and Gas (National Research University), 119991, Moscow, Russia

    I. V. Perov

Authors
  1. M. V. Magomedova
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  2. A. V. Starozhitskaya
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  3. M. I. Afokin
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  4. I. V. Perov
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  5. M. A. Kipnis
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  6. G. I. Lin
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Corresponding author

Correspondence to M. I. Afokin.

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The authors declare that they have no conflicts of interest requiring disclosure in this article.

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Translated by S. Zatonsky

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Magomedova, M.V., Starozhitskaya, A.V., Afokin, M.I. et al. Mathematical Modeling and Calculation of the Methanol Production Process via Carbon Dioxide Hydrogenation. Pet. Chem. 60, 1244–1250 (2020). https://doi.org/10.1134/S0965544120110146

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  • DOI: https://doi.org/10.1134/S0965544120110146

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