Abstract
Results of a study of the reaction products of asphaltene sulfonation with sulfuric acid in various temperature and time ranges have been described. The maximum sulfur content in sulfonated cation exchangers at an asphaltene sulfonation temperature of 100 and 120°С and a reaction time of 2 h has been determined. The maximum static exchange capacity of 4.3 meq/g has been found for the products of sulfonation with a sulfuric acid–oleum mixture. The asphaltene-based strongly acidic sulfocationite has been tested in the 2,2-dimethyl-1,3-dioxolane synthesis reaction.
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ACKNOWLEDGMENTS
The authors thank the staff of the Distributed Collective Spectral-Analytical Center for Studying the Structure, Composition, and Properties of Substances and Materials of the Federal Research Center Kazan Scientific Center of the Russian Academy of Sciences for the conducted studies.
Funding
This work was performed under a state task to Federal Research Center Kazan Scientific Center of the Russian Academy of Sciences.
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Foss, L.E., Shabalin, K.V., Musin, L.I. et al. Synthesis of Asphaltene-Based Strongly Acidic Sulfonated Cation Exchangers and Determination of Their Catalytic Properties in the 2,2-Dimethyl-1,3-Dioxolane Synthesis Reaction. Pet. Chem. 60, 709–715 (2020). https://doi.org/10.1134/S0965544120060055
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DOI: https://doi.org/10.1134/S0965544120060055