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Ultrahigh-Resolution Mass Spectrometry Analysis of Ozonation Products of Petroleum Nitrogen Compounds

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Abstract

Changes that occur at the molecular level in the composition of nitrogen compounds of a petroleum sample from the Yuzno-Yagunskoe field during ozonation have been studied by ultrahigh-resolution Fourier transform ion cyclotron resonance mass spectrometry in soft ionization modes. It has been found that N1Ox-containing products accumulate to form new classes of compounds, namely, N1O2, N1O3, N1O4, N1O5, N1O6, and N1O7, while N1 classes undergo degradation. Ozonation of 50% of the feedstock leads to a ~30% decrease in the number of identified empirical formulas of pyridine bases (N1 class).

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Funding

This work was supported by the Russian Science Foundation, project no. 18-73-00342.

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Authors and Affiliations

  1. Gubkin Russian State University of Oil and Gas, 119991, Moscow, Russia

    A. V. Stavitskaya & R. Z. Safieva

  2. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334, Moscow, Russia

    M. L. Konstantinova & V. V. Podmasteriev

Authors
  1. A. V. Stavitskaya
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  2. M. L. Konstantinova
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  3. V. V. Podmasteriev
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  4. R. Z. Safieva
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Corresponding authors

Correspondence to A. V. Stavitskaya or R. Z. Safieva.

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Translated by M. Timoshinina

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Stavitskaya, A.V., Konstantinova, M.L., Podmasteriev, V.V. et al. Ultrahigh-Resolution Mass Spectrometry Analysis of Ozonation Products of Petroleum Nitrogen Compounds. Pet. Chem. 59, 1147–1152 (2019). https://doi.org/10.1134/S0965544119100104

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  • DOI: https://doi.org/10.1134/S0965544119100104

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