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Nonoxidative Conversion of Methane to Aromatic Hydrocarbons in the Presence of ZSM-5 Zeolites Modified with Molybdenum and Rhenium

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Abstract

The nonoxidative conversion of methane to aromatic hydrocarbons in the presence of a high-silica ZSM-5 zeolite modified with molybdenum and rhenium nanopowders has been studied. Data on the acid characteristics of the catalysts have been derived by temperature-programmed desorption of ammonia. The microstructure and composition of the Re/ZSM-5 and Re–Mo/ZSM-5 catalyst systems have been studied by transmission electron microscopy. It has been shown that modification of a Mo-containing zeolite with rhenium leads to an increase in the activity and stability of the catalyst in the methane dehydroaromatization reaction.

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ACKNOWLEDGMENTS

This work was performed under the Basic Research Program of State Academies of Sciences, project no. V.46.2.1.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, Tomsk, Russia

    A. A. Stepanov, L. L. Korobitsyna & A. V. Vosmerikov

  2. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. I. Zaikovskii

  3. Novosibirsk National Research State University, Novosibirsk, Russia

    V. I. Zaikovskii

Authors
  1. A. A. Stepanov
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  2. V. I. Zaikovskii
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  3. L. L. Korobitsyna
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  4. A. V. Vosmerikov
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Corresponding author

Correspondence to A. V. Vosmerikov.

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Translated by M. Timoshinina

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Stepanov, A.A., Zaikovskii, V.I., Korobitsyna, L.L. et al. Nonoxidative Conversion of Methane to Aromatic Hydrocarbons in the Presence of ZSM-5 Zeolites Modified with Molybdenum and Rhenium. Pet. Chem. 59, 91–98 (2019). https://doi.org/10.1134/S0965544119010146

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  • DOI: https://doi.org/10.1134/S0965544119010146

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