Skip to main content
Log in

Destructive Conversion of Gas Oil in the Presence of a Nickel-Based Nanosized Catalyst

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

The decomposition of nickel 2-ethylhexanoate by heating in a vacuum gas oil (VGO) medium at 355–365°С has been found to yield nickel and nickel sulfide nanoparticles. The size of the particles is 20–120 nm. The catalytic cracking of VGO in the presence of these nickel-containing particles provides a 70.15% yield of the distillate with a boiling point up to 220°C. The structural-group composition of the products of VGO cracking in the presence of nickel-based nanoscale catalysts has been studied using gas chromatography–mass spectrometry. The group composition of samples containing cracked products has been analyzed to cover eleven classes of organic compounds. The structural composition of the test samples has been considered with respect to eight groups of compounds, of which three include two to three classes of compounds. In the catalytic cracking of VGO, the concentration of alkanes increases by 3.11% and that of alkenes and alkylbenzenes decreases by 1.31 and 2.59%, respectively, as compared to their content in the products of VGO distillation without a catalyst.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. I. Chorkendorff and J. W. Niemantsverdriet, Concepts of Modern Catalysis and Kinetics (Wiley–VCH, Weinheim, 2003).

    Book  Google Scholar 

  2. O. V. Krylov, Heterogeneous Catalysis (Akademkniga, Moscow, 2004) [in Russian].

    Google Scholar 

  3. S. N. Khadzhiev, Pet. Chem. 51, 1 (2011).

    Article  CAS  Google Scholar 

  4. N. L. Solodova and N. A. Terent’eva, Vestn. Kazansk. Gos. Univ. 16, 209 (2013).

    Google Scholar 

  5. Yu. P. Suvorov, A. A. Krichko, and S. N. Khadzhiev, Pet. Chem. 40, 193 (2000).

    CAS  Google Scholar 

  6. S. Alkhaldi and M. M. Husein, Energy Fuels 28, 643 (2014).

    Article  CAS  Google Scholar 

  7. E. S. Brodskii, Doctoral Dissertation in Chemistry (Moscow, 2004)).

    Google Scholar 

  8. R. N. Galiakhmetov, O. M. Sudakova, A. G. Mustafin, and I. A. Mustafin, Int. J. Appl. Eng. Res. 10, 41864 (2015).

    Google Scholar 

  9. I. A. Mustafin, O. M. Sudakova, R. N. Galiakhmetov, et al., Mir Nefteprod., No. 12, 18 (2016).

    Google Scholar 

  10. R. N. Galiakhmetov and A. G. Mustafin, RU Patent No. 2472842 (2013).

  11. R. N. Galiakhmetov and A. G. Mustafin, RU Patent No. 2485167 (2013).

  12. R. N. Galiakhmetov and A. G. Mustafin, RU Patent No. 2486130 (2013).

  13. L. I. Mirkin, Handbook of X-ray Diffraction Analysis of Polycrystalline Materials, Ed. by Ya. S. Umanskii (Fizmatlit, Moscow, 1961) [in Russian].

  14. A. T. Lebedev, Mass Spectrometry in Organic Chemistry (BINOM, Moscow, 2003) [in Russian].

    Google Scholar 

  15. E. V. Urzhumova, L. M. Velichkina, A. V. Vosmerikov, and A. E. Ermakov, Catal. Ind. 3, 157 (2011).

    Article  Google Scholar 

  16. P. Sykes, A Guidebook to Mechanism in Organic Chemistry (Pearson Education, Harlow, 1986) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to I. A. Mustafin.

Additional information

Original Russian Text © I.A. Mustafin, M.F. Abdullin, O.M. Sudakova, A.G. Mustafin, R.N. Galiakhmetov, E.R. Valinurova, 2018, published in Neftekhimiya, 2018, Vol. 58, No. 3.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mustafin, I.A., Abdullin, M.F., Sudakova, O.M. et al. Destructive Conversion of Gas Oil in the Presence of a Nickel-Based Nanosized Catalyst. Pet. Chem. 58, 379–386 (2018). https://doi.org/10.1134/S0965544118050122

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544118050122

Keywords

Navigation