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Experimental Study on Homogeneous Catalytic Upgrading of Heavy Oil

Abstract

Four catalyst precursors were prepared to assess the performance on the upgrading process of heavy oil. It has been showed that viscosity of Lukeqin heavy oil was decreased significantly, which revealed a viscosity reduction ratio of up to 99.28% with a catalyst precursor concentration of 0.12 wt %, reaction temperature of 365°С and reaction time of 40 min. Analysis of the oil after upgrading showed an obviously change in the composition of hydrocarbon components. The increase of light fractions after reaction improved the properties of heavy oil which is benefit to the pipeline transportation and downstream refining. Meanwhile, the mechanism of upgrading was also investigated. This work proved that heavy oil can be effectively upgraded with the catalyst precursor of petroleum acid iron.

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References

  1. R. Hashemi, N. N. Nassar, and P. P. Almao, Energy Fuels 27, 2194 (2013).

    Article  CAS  Google Scholar 

  2. Y. L. Chen, Y. Q. Wang, J. Y. Lu, and C. Wu, Fuel 88, 1426 (2009).

    Article  CAS  Google Scholar 

  3. W. C. Angle, L. Lue, T. Dabros, and H. A. Hamza, Energy Fuels 19, 2014 (2005).

    Article  CAS  Google Scholar 

  4. J. G. Weissman, Fuel Process Technol. 50, 199 (1997).

    Article  CAS  Google Scholar 

  5. W. C. Lyons, G. J. Plisga, and M. D. Lorenz, Standard Handbook of Petroleum and Natural Gas Engineering (Houston, USA, 2005).

    Google Scholar 

  6. L. A. Pinedaperez, L. Carbognani, R. J. Spencer, B. Maini, and P. Pereiraalmao, Energy Fuels 24, 5947 (2010).

    Article  CAS  Google Scholar 

  7. S. Bagci and M.V. Kok, Fuel Process Technol. 74, 65 (2001).

    Article  CAS  Google Scholar 

  8. C. Metsai, W. Kantapong, C. Wiwan, B. Thanapong, T. O. Svein, and M. Kreangkrai, Earth Planet Sci. Lett. 6, 326 (2013).

    Article  Google Scholar 

  9. U. U. Amanam and A. R. Kovscek, J. Petrol. Sci. Eng. 152, 406 (2017).

    Article  CAS  Google Scholar 

  10. B. He, Q. Chen, and L. M. Castanier, Improved in situ Combustion Performance with Metallic Salt Additives (Irvine, USA, 2005).

    Book  Google Scholar 

  11. M. Ramirez-Garnica, J. H. Perez, M. Cabrera-Reyes, P. Schacht-Hernandez, and D. D. Mamora, Increase Oil Recovery of Heavy Oil in Combustion Tube Using a New Catalyst Based Nickel Ionic Solution (Calgary, Canada, 2008).

    Book  Google Scholar 

  12. T. Kar and B. Hascakir, J. Petrol. Sci. Eng. 146, 746 (2017).

    Google Scholar 

  13. I. M. Abdrafikova, G. P. Kayukova, S. M. Petrov, A. I. Ramazanova, R. Z. Musin, and V. I. Morozov, Petr. Chem. 55, 104 (2015).

    Article  CAS  Google Scholar 

  14. P. D. Clark, J. B. Hyne, and J. D. Tyrer, Fuel 63, 1649 (1984).

    Article  CAS  Google Scholar 

  15. H. M. Wang, X. D. Tang, K. Q. Meng, Y. X. Cui, Z. H. Wang, and F. Wang, Fine Chemicals 26, 566 (2009).

    CAS  Google Scholar 

  16. X. D. Tang, H. Zhu, J. J. Li, F. Wang, and D. Y. Qing, Petrol. Sci. Technol. 33, 1721 (2015).

    Article  CAS  Google Scholar 

  17. I. Anugwom, P. Mäki-Arvela, T. Salmi, and J. P. Mikkola, Blood. 2, 796 (2011).

    CAS  Google Scholar 

  18. S. A. Dharaskar, K. L. Wasewar, M. N. Varma, and D. Z. Shende, J. Energy 23, 2013 (2013).

    Google Scholar 

  19. Y. Yu and K. Li, Petrol. Sci. Technol. 31, 2569 (2013).

    Article  CAS  Google Scholar 

  20. H. Orbey and S. I. Sandler, Can. J. Chem. Eng. 71, 437 (1993).

    Article  CAS  Google Scholar 

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Correspondence to J. J. Li.

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Published in Russian in Neftekhimiya, 2017, Vol. 57, No. 6, pp. 639–644.

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Tang, X.D., Chen, X.D., Li, J.J. et al. Experimental Study on Homogeneous Catalytic Upgrading of Heavy Oil. Pet. Chem. 57, 1018–1023 (2017). https://doi.org/10.1134/S0965544117120143

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  • DOI: https://doi.org/10.1134/S0965544117120143

Keywords

  • heavy oil
  • catalytic upgrading
  • viscosity reduction
  • catalyst precursor
  • petroleum acid