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Petroleum Chemistry

, Volume 57, Issue 12, pp 1012–1017 | Cite as

Analysis of Sour Oil Ozonation Products by Ultra-High Resolution Mass-Spectrometry

  • A. V. Stavitskaya
  • M. L. Konstantinova
  • S. D. Razumovskii
  • R. Z. Safieva
  • V. A. Vinokurov
Article

Abstract

Ozonation products of sour crude oil have been determined at the molecular level by means of ion cyclotron resonance Fourier-transform mass spectrometry in soft ionization modes. It has been shown that a proper choice of ozonation conditions makes it possible to selectively ozonize heteroatomic nitrogen, sulfur, and oxygen compounds, such as pyrrole derivatives, sulfides, disulfides, thiophene derivatives, resins, and asphaltenes. It has been found that the hydrocarbon portion of the oil is not ozonized under the given conditions.

Keywords

ozone ozonation sour oil heteroatomic petroleum compounds petroleum sulfur compounds oxidative desulfurization ultra-high resolution mass spectrometry 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • A. V. Stavitskaya
    • 1
  • M. L. Konstantinova
    • 2
  • S. D. Razumovskii
    • 2
  • R. Z. Safieva
    • 1
  • V. A. Vinokurov
    • 1
  1. 1.Gubkin Russian State University of Oil and GasMoscowRussia
  2. 2.Emanuel Institute of Biochemical PhysicsRussian Academy of SciencesMoscowRussia

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