Abstract
It is shown that the effective synthesis of methanol may be performed in the presence of ultrafine catalyst systems formed by drop thermolysis in situ in a slurry reactor. Using the X-ray powder diffraction and FTIR spectroscopy data on the evolution of Cu–Zn–Al-containing catalyst dispersion during activation and catalysis, possible reasons for ultrafine catalyst deactivation are considered.
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Original Russian Text © M.I. Ivantsov, M.V. Kulikova, M.A. Gubanov, O.S. Dement’eva, M.V. Chudakova, G.N. Bondarenko, S.N. Khadzhiev, 2017, published in Nanogeterogennyi Kataliz, 2017, Vol. 2, No. 1, pp. 23–28.
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Ivantsov, M.I., Kulikova, M.V., Gubanov, M.A. et al. Methanol synthesis in a three-phase slurry reactor with ultrafine catalysts. Pet. Chem. 57, 571–575 (2017). https://doi.org/10.1134/S0965544117070027
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DOI: https://doi.org/10.1134/S0965544117070027