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Oxidative dehydrogenation of cyclohexane over modified zeolite catalysts

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Abstract

The catalytic activity of modified zeolites in selective oxidative dehydrogenation of cyclohexane has been studied. It has been established that polymetallic zeolite catalyst, namely, CuZnCoCr-clinoptilolite (0.5% Cu2+, 0.2% Zn2+; 0.1% Co2+; 0.1% Cr3+) manifests the highest activity in the reaction under consideration. The kinetic scheme of the reaction mechanism has been proposed, and a kinetic model of the process has been developed on the basis of stepwise mechanism schemes. The numerical values of the kinetic parameters are calculated.

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Authors and Affiliations

  1. Nagiev Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan, pr. G. Dzhavida 113, Baku, AZ1141, Azerbaijan

    A. M. Aliev, Z. A. Shabanova, U. M. Nadzhaf-Kuliev & S. M. Medzhidova

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  1. A. M. Aliev
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  2. Z. A. Shabanova
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  3. U. M. Nadzhaf-Kuliev
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  4. S. M. Medzhidova
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Correspondence to A. M. Aliev.

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Original Russian Text © A.M. Aliev, Z.A. Shabanova, U.M. Nadzhaf-Kuliev, S.M. Medzhidova, 2016, published in Neftekhimiya, 2016, Vol. 56, No. 4, pp. 407–413.

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Aliev, A.M., Shabanova, Z.A., Nadzhaf-Kuliev, U.M. et al. Oxidative dehydrogenation of cyclohexane over modified zeolite catalysts. Pet. Chem. 56, 639–645 (2016). https://doi.org/10.1134/S0965544116070021

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  • DOI: https://doi.org/10.1134/S0965544116070021

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