Skip to main content
SpringerLink
Log in

Dehydration of 2,3-butanediol over zeolite catalysts

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

2,3-Butanediol as a product of biomass processing is a cheap alternative raw material for synthesis of methyl ethyl ketone (MEK) and butadiene-1,3. The catalytic activity of Al- and Zr-containing BEA zeolites and an alumina-based catalyst in 2,3-butanediol dehydration has been investigated. It has been shown that the presence of Brönsted (H-BEA) or Lewis (Al2O3) sites leads to the selective formation of MEK and the combination of two types of sites (Zr-BEA) facilitates the formation of heavy products of condensation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Motwani, R. Seth, H. F. Daginawala, and R. Khanna, Bioresour. Technol. 44, 187 (1993).

    Article  CAS  Google Scholar 

  2. L.-Q. Jiang, Z. Fang, F. Guo, and L. Yang, Bioresour. Technol. 107, 405 (2012).

    Article  CAS  Google Scholar 

  3. M. Voloch, N. B. Jansen, M. R. Ladisch, et al., Comprehensive Biotechnology, vol. 3: The Practice of Biotechnology: Current Commodity Products, Ed. by H. W. Blanch, S. Drew, and D. I. C. Wang (Pergamon, Oxford, 1985), p. 933.

  4. C.-F. Huang, Y.-F. Jiang, G.-L. Guo, and W.-S. Hwang, Bioresour. Technol. 135, 446 (2013).

    Article  CAS  Google Scholar 

  5. M. Köpke, C. Mihalcea, F. Liew, et al., Appl. Environ. Microbiol. 77, 5467 (2011).

    Article  Google Scholar 

  6. M. Anvari and M. R. S. Motlagh, J. Biomed. Biotechnol. 2011, 1 (2011).

    Article  Google Scholar 

  7. L. Zhenhua, H. Wenzhou, and M. Hao, Chin. J. Chem. Eng. 14, 676 (2006).

    Article  Google Scholar 

  8. US Patent No. 7 282 613 (2007).

  9. US Patent No. 4 453 015 (1984).

  10. K. Frolich and C. E. Morrell, Chem. Eng. News 21, 1138 (1943).

    Article  CAS  Google Scholar 

  11. W. C. White, Chem.-Biol. Interact. 166, 10 (2007).

    Article  CAS  Google Scholar 

  12. US Patent 4504692 1985

  13. N. L. Morrow, Environ. Health Perspect. 86, 7 (1990).

    Article  CAS  Google Scholar 

  14. I. Bucsi, A. Molnar, and M. Bartok, Tetrahedron 50, 8195 (1994).

    Article  CAS  Google Scholar 

  15. B. Torok, I. Bucsi, T. Beregszaszi, et al., J. Mol. Catal. A: Chem. 107, 305 (1996).

    Article  Google Scholar 

  16. J. Lee, J. B. Grutzner, W. E. Walters, and W. N. Delgass, Stud. Surf. Sci. Catal. 130, 2603 (2000).

    Article  Google Scholar 

  17. W. Zhang, D. Yu, X. Jia, and H. Huang, Green Chem. 14, 3441 (2012).

    Article  CAS  Google Scholar 

  18. S. Sato, F. Sato, H. Gotoh, and Y. Yamada, ACS Catal. 3, 721 (2013).

    Article  CAS  Google Scholar 

  19. H. Duan, Y. Yamada, and S. Sato, Appl. Catal., A 491, 163 (2015).

    Article  CAS  Google Scholar 

  20. B. O. Dalla Costa, M. A. Peralta, and C. A. Querini, Appl. Catal., A 472, 53 (2014).

    Article  CAS  Google Scholar 

  21. M. Han, S. X. Lin, and E. Roduner, Appl. Catal., A 243, 75 (2003).

    Article  Google Scholar 

  22. T. Yashima, Z. B. Wang, A. Kamo, et al., Catal. Today 29, 279 (1996).

    Article  CAS  Google Scholar 

  23. V. L. Sushkevich, D. Palagin, and I. I. Ivanova, ACS Catal. 5, 4833 (2015).

    Article  CAS  Google Scholar 

  24. Y. Nie, W. Niah, S. Jaenicke, and G.-K. Chuah, J. Catal. 248, 1 (2007).

    Article  CAS  Google Scholar 

  25. S. Dzwigaj and M. Che, J. Phys. Chem. B 110, 12490 (2006).

    Article  CAS  Google Scholar 

  26. E. B. Lami, F. Fajula, D. Anglerot, and T. des Courieres, Microporous Mater. 1, 237 (1993).

    Article  CAS  Google Scholar 

  27. Y. J. O. Asenciosa and M. R. Sun-Kou, Appl. Surf. Sci. 258, 10002 (2012).

    Article  Google Scholar 

  28. J. N. Kondo, R. Nishitani, E. Yoda, et al., Phys. Chem. Chem. Phys. 12, 11576 (2010).

    Article  CAS  Google Scholar 

  29. V. L. Sushkevich, I. I. Ivanova, S. Tolborg, and E. Taarning, J. Catal. 316, 121 (2014).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, Russia

    M. A. Nikitina, V. L. Sushkevich & I. I. Ivanova

Authors
  1. M. A. Nikitina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. L. Sushkevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. I. Ivanova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. I. Ivanova.

Additional information

Original Russian Text © M.A. Nikitina, V.L. Sushkevich, I.I. Ivanova, 2016, published in Neftekhimiya, 2016, Vol. 56, No. 3, pp. 248–254.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nikitina, M.A., Sushkevich, V.L. & Ivanova, I.I. Dehydration of 2,3-butanediol over zeolite catalysts. Pet. Chem. 56, 230–236 (2016). https://doi.org/10.1134/S0965544116030099

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544116030099

Keywords

Search

Navigation