Abstract
The use of modified forms of zeolite-containing rocks (ZCRs) that comprise a mixture of zeolites as catalysts for the dehydration of methanol to dimethyl ether has been studied. Results of examination of the effect of chemical modification on the activity and stability of the catalysts have been described. It has been shown that modified rocks containing mordenite and clinoptilolite can be in principle used as methanol conversion catalysts. The contribution of each of the zeolite components to the catalyst performance has been determined.
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References
A. Ya. Rozovskii, Khim. Interes. Ustoich. Razvit. 13, 701 (2005).
Review of Natural Zeolite Market in the CIS, 2nd ed. (InforMain, Moscow, 2010) [in Russian].
S. Hassanpour, F. Yaripour, and M. Taghizadeh, Fuel Process. Technol. 91, 1212 (2010).
S. Hassanpour, M. Taghizadeh, and F. Yaripour, Ind. Eng. Chem. Res. 49, 4063 (2010)
M. Kasaie and M. Sohrabi, J. Mex. Chem. Soc. 53, 233 (2009).
K.-S. Ha, Y.-J. Lee, J. W. Bae, et al., Appl. Catal. A: Gen. 395, 95 (2011).
S. R. Blaszkowski and R. A. van Santen, J. Phys. Chem. B 101, 2292 (1997).
S. R. Blaszkowski and R. A. van Santen, J. Am. Chem. Soc. 118, 5152 (1996).
R. Shah, J. D. Gale and M. C. Payne, J. Phys. Chem. B 101, 4787 (1997).
S. B. Sharma, B. L. Meyers, D. T. Chen, et al., Appl. Catal. A: Gen. 102, 253 (1993).
L. Heeribout, P. Batamack, C. Dorémieux-Morin, et al., Colloids Surf. A: Physicochem. Eng. Aspects 115, 229 (1996).
N. P. Samchenko, I. S. Alcheev, and T. Yu. Sliva, Teor. Eksp. Khim. 25, 244 (1989).
S. J. Royaee, C. Falamaki, M. Sohrabi, and S. S. Ashraf Talesh, Appl. Catal. A: Gen. 338, 114 (2008).
M. Kasai and M. Sohrabi, J. Mex. Chem. Soc. 53, 233 (2009).
A. D. Kustovs’ka, Visnik NAU, No. 1, 192 (2005).
E. E. Grechanovskaya and V. S. Mel’nikov, Mineral. Zh. 28, 5 (2006).
A. D. Onishchenko, N. V. Turutina, F. M. Bobonich, and V. G. Il’in, Ukr. Khim. Zh. 54, 131 (1988).
S. Jiang, J.-S. Hwang, T. Jin, et al., Bull. Korean Chem. Soc. 25, 185 (2004).
M.-F. Reyniers, Y. Tang, and G. B. Marin, Appl. Catal. A: Gen. 202, 65 (2000).
Yu. G. Voloshina, L. K. Patrilyak, V. V. Ivanenko, and K. I. Patrilyak, Teor. Eksp. Khim. 45, 249 (2009).
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Original Russian Text © A.D. Kustovskaya, E.I. Kosenko, 2014, published in Neftekhimiya, 2014, Vol. 54, No. 2, pp. 141–145.
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Kustovskaya, A.D., Kosenko, E.I. Catalytic activity of natural zeolites in the conversion of methanol to dimethyl ether. Pet. Chem. 54, 137–141 (2014). https://doi.org/10.1134/S0965544114020054
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DOI: https://doi.org/10.1134/S0965544114020054