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Ethylene oligomerization on the chromium ethylhexanoate-triethylaluminum-2,5-dimethylpyrrol catalytic system in the presence of carbon tetrachloride

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Abstract

The kinetics of the selective ethylene oligomerization reaction on the chromium(III) ethylhexanoate-Al(C2H5)3-2,5-dimethylpyrrol homogeneous catalytic system in the presence of CCl4 has been studied. The reaction rate order in ethylene, the activation energy, and the selectivity of reaction for 1-hexene have been determined.

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Authors and Affiliations

  1. Kazan State Technological University, Kazan, Russia

    I. I. Khasbiullin & Kh. E. Kharlampidi

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    I. I. Khasbiullin & G. P. Belov

  3. Irkutsk State University, Irkutsk, Russia

    A. I. Vil’ms

Authors
  1. I. I. Khasbiullin
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  2. G. P. Belov
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  3. Kh. E. Kharlampidi
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  4. A. I. Vil’ms
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Correspondence to I. I. Khasbiullin.

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Original Russian Text © I.I. Khasbiullin, G.P. Belov, Kh.E. Kharlampidi, A.I. Vil’ms, 2011, published in Neftekhimiya, 2011, Vol. 51, No. 6, pp. 450–455.

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Khasbiullin, I.I., Belov, G.P., Kharlampidi, K.E. et al. Ethylene oligomerization on the chromium ethylhexanoate-triethylaluminum-2,5-dimethylpyrrol catalytic system in the presence of carbon tetrachloride. Pet. Chem. 51, 442–447 (2011). https://doi.org/10.1134/S0965544111060090

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  • DOI: https://doi.org/10.1134/S0965544111060090

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