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Selective dimerization of styrene to 1,3-diphenylbutene-1 in the presence of [(acac)Pd(PAr3)2]BF4/BF3OEt2 catalytic systems

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Abstract

Selective dimerization of styrene to 1,3-diphenylbutene-1 in the presence of [(acac)Pd(PAr3)2]BF4 + BF3OEt2 catalytic systems, where R = C6H5, o-CH3C6H4, p-CH3C6H4, or o-CH3OC6H4, has been studied. Under the optimal conditions (B/Pd = 8, T = 75°C, R = C6H5), the conversion of styrene to the products exceeds the conversion for the known analogs and reaches 1.5 tons of styrene/g-atom of palladium with amounts of dimers and trimers of 91 and 9%, respectively. The dimers consist of up to 100% 1,3-diphenylbutene-1 with a trans/cis isomer ratio of 95/5.

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Authors and Affiliations

  1. Irkutsk State University, ul. Karla Marksa 1, Irkutsk, 664003, Russia

    D. S. Suslov, V. S. Tkach, M. V. Bykov & M. V. Belova

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  1. D. S. Suslov
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  2. V. S. Tkach
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  3. M. V. Bykov
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  4. M. V. Belova
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Correspondence to V. S. Tkach.

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Original Russian Text © D.S. Suslov, V.S. Tkach, M.V. Bykov, M.V. Belova, 2011, published in Neftekhimiya, 2011, Vol. 51, No. 3, pp. 169–175.

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Suslov, D.S., Tkach, V.S., Bykov, M.V. et al. Selective dimerization of styrene to 1,3-diphenylbutene-1 in the presence of [(acac)Pd(PAr3)2]BF4/BF3OEt2 catalytic systems. Pet. Chem. 51, 157–163 (2011). https://doi.org/10.1134/S0965544111030157

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  • DOI: https://doi.org/10.1134/S0965544111030157

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