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Methane conversion to valuable chemicals over nanostructured Mo/ZSM-5 catalysts

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Abstract

Results of the ongoing study of nonoxidative methane dehydroaromatization (DHA) over Mo/ZSM-5 catalysts have been analyzed. The effects of the composition, preparation procedure, pretreatment, and the CH4 DHA reaction conditions on the physicochemical and catalytic properties of Mo/ZSM-5 catalysts have been discussed. The data on Mo-containing active sites, the methane DHA reaction mechanism, and the nature of carbonaceous deposits have been considered. The principal causes of the deactivation of Mo/ZSM-5 catalysts and means of their regeneration have been revealed. Approaches to the improvement of the methane DHA process and trends of its further development have been detailed.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    Z. R. Ismagilov, E. V. Matus, M. A. Kerzhentsev, L. T. Tsikoza & I. Z. Ismagilov

  2. Sokol’skii Institute of Organic Catalysis and Electrochemistry, Almaty, Republic of Kazakhstan

    K. D. Dosumov

  3. Bashkir State University, Ufa, Russia

    A. G. Mustafin

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  1. Z. R. Ismagilov
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  2. E. V. Matus
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  3. M. A. Kerzhentsev
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  4. L. T. Tsikoza
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  5. I. Z. Ismagilov
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  6. K. D. Dosumov
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  7. A. G. Mustafin
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Correspondence to M. A. Kerzhentsev.

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Original Russian Text © Z.R. Ismagilov, E.V. Matus, M.A. Kerzhentsev, L.T. Tsikoza, I.Z. Ismagilov, KD. Dosumov, A.G. Mustafin, 2011, published in Neftekhimiya, 2011, Vol. 51, No. 3, pp. 186–198.

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Ismagilov, Z.R., Matus, E.V., Kerzhentsev, M.A. et al. Methane conversion to valuable chemicals over nanostructured Mo/ZSM-5 catalysts. Pet. Chem. 51, 174–186 (2011). https://doi.org/10.1134/S0965544111020058

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