Abstract
Mono- and bimetallic Rh and Rh-Co complexes containing oligoallene ligands were synthesized. Their catalytic activity was examined in the hydrogenation of unsaturated compounds, such as isoprene, hexene-1, and toluene. The catalytic activity of Rh(DMA)ol and Rh-Co(DMA)ol was shown to be 16 800 and 23000 mol/(mol h) in the hydrogenation of hexene-1 and 72 and 90 mol/(mol h) in the hydrogenation of toluene, respectively. Isoprene is hydrogenated completely: the rate curves exhibit two portions corresponding to hydrogenation of both double bonds. The catalytic activity of palladium oligodimethylallene complexes deposited on an inorganic support (γ-Al2O3) in isoprene hydrogenation depends on the support preparation procedure, the particle size, and the metal loading on the surface. Heterogenization of the homogeneous mono- and bimetallic Rh and Pd complexes somewhat enhances the catalytic activity in hydrogenation of the given substrates.
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Original Russian Text © E.M. Khar’kova, L.E. Rozantseva, V.M. Frolov, 2010, published in Neftekhimiya, 2010, Vol. 50, No. 3, pp. 226–230.
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Khar’kova, E.M., Rozantseva, L.E. & Frolov, V.M. Hydrogenation of unsaturated hydrocarbons catalyzed by homogeneous and supported Rh, Rh-Co, and Pd, Pd-Ni complexes with oligomeric allene ligands. Pet. Chem. 50, 214–219 (2010). https://doi.org/10.1134/S0965544110030060
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DOI: https://doi.org/10.1134/S0965544110030060