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Styrene oligomerization catalyzed by zeolites of different structural types

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Abstract

It was shown that styrene oligomerization in the presence of the zeolite ZSM-12 in a solvent (chlorobenzene) as well as without it proceeds with a high conversion (98–100 wt %) and a high selectivity for linear dimers (up to 82%). The main oligomerization products in the presence of the zeolite Beta are dimers (70–80%), mostly the linear isomer trans-1,3-diphenylbut-1-ene. In the presence of the less active zeolite Y, styrene gives a complex mixture of oligomers in which dimers (53–60%, in chlorobenzene) or dimers and trimers (60–80%, in bulk) are predominant.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, Ufa, Russia

    N. G. Grigor’eva, R. R. Talipova, L. Ph. Korzhova, S. V. Bubennov, B. I. Kutepov & U. M. Dzhemilev

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  1. N. G. Grigor’eva
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  2. R. R. Talipova
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  3. L. Ph. Korzhova
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  4. S. V. Bubennov
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  5. B. I. Kutepov
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  6. U. M. Dzhemilev
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Correspondence to N. G. Grigor’eva.

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Original Russian Text © N.G. Grigor’eva, R.R. Talipova, L.Ph. Korzhova, S.V. Bubennov, B.I. Kutepov, U.M. Dzhemilev, 2010, published in Neftekhimiya, 2010, Vol. 50, No. 2, pp. 125–129.

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Grigor’eva, N.G., Talipova, R.R., Korzhova, L.P. et al. Styrene oligomerization catalyzed by zeolites of different structural types. Pet. Chem. 50, 129–134 (2010). https://doi.org/10.1134/S0965544110020088

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  • DOI: https://doi.org/10.1134/S0965544110020088

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