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Effect of zinc-subgroup metal salts on the formation of hydroperoxide during the oxidation of cumene

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Abstract

The oxidation of cumene catalyzed by zinc, cadmium, and mercury 2-ethylhexanoates was studied. It was found that the catalytic effect weakens in the order Cd-Hg-Zn. The influence of an initiator on the cumene hydroperoxide buildup in the presence of group IIB metal compounds was revealed.

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References

  1. L. V. Petrov, V. M. Solyanikov, and Z. Ya. Petrova, Dokl. Akad. Nauk SSSR 230, 366 (1976).

    CAS  Google Scholar 

  2. B. V. Galabitskii, Candidate’s Dissertation in Chemistry (Chernogolovka, 1975).

  3. V. K. Tsyskovskii, S. S. Botkina, E. K. Prokof’ev, and Yu. L. Moskovich, Zh. Prikl. Khim. (Leningrad) 49, 1299 (1972).

    Google Scholar 

  4. V. A. Simanov and M. S. Nemtsov, Zh. Org. Khim. 30, 1420 (1970).

    Google Scholar 

  5. A. V. Nedoseko and K. A. Chervinskii, Khim. Prom-st., No. 7, 505 (1971).

  6. I. Drimus and A. Lupu, Rev. Roum. Chem. 17, 1409 (1972).

    CAS  Google Scholar 

  7. O. E. Levanevskii and T. Zhumadylov, Kinet. Katal., No. 9, 29 (1968).

  8. L. P. Velyutin, V. M. Potekhin, and V. I. Ovchinnikov, Zh. Prikl. Khim. (Leningrad) 53(3), 604 (1980).

    CAS  Google Scholar 

  9. L. P. Velyutin, V. M. Potekhin, and V. V. Ovchinnikov, Zh. Prikl. Khim. (Leningrad) 53(4), 701 (1980).

    CAS  Google Scholar 

  10. Kh. E. Kharlampidi, N. N. Batyrshin, and V. G. Ivanov, Neftekhimiya 20, 708 (1980).

    CAS  Google Scholar 

  11. N. M. Nurullina, N. N. Batyrshin, and Kh. E. Kharlampidi, Neftekhimiya 44, 475 (2004) [Pet. Chem. 44, 441 (2004)].

    CAS  Google Scholar 

  12. N. M. Nurullina, Candidate’s Dissertation in Chemistry (Kazan, 2005).

  13. V. L. Antonovskii and M. M. Buzlanova, Analitical Chemistry of Organic Peroxide Compounds (Khimiya, Moscow, 1978) [in Russian].

    Google Scholar 

  14. V. A. Belyaev and M. S. Nemtsov, Zh. Org. Khim. 31, 3855 (1961).

    CAS  Google Scholar 

  15. N. M. Emanuel, E. T. Denisov, and Z. K. Maizus, Chain Oxidation Reactions of Hydrocarbons in the Liquid phase (Nauka, Moscow, 1965) [in Russian].

    Google Scholar 

  16. N. M. Emanuel, G. P. Gladyshev, E. T. Denisov, et al., Regulations for Testing Chemicals as Polymer Stabilizers (Chernogolovka, 1976) [in Russian].

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Authors and Affiliations

  1. Kazan State University of Technology, Kazan, Russia

    N. M. Nurullina, N. N. Batyrshin & Kh. E. Kharlampidi

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  1. N. M. Nurullina
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  2. N. N. Batyrshin
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  3. Kh. E. Kharlampidi
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Correspondence to N. M. Nurullina.

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Original Russian Text © N.M. Nurullina, N.N. Batyrshin, Kh.E. Kharlampidi, 2009, published in Neftekhimiya, 2009, Vol. 49, No. 5, pp. 405–408.

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Nurullina, N.M., Batyrshin, N.N. & Kharlampidi, K.E. Effect of zinc-subgroup metal salts on the formation of hydroperoxide during the oxidation of cumene. Pet. Chem. 49, 385–388 (2009). https://doi.org/10.1134/S0965544109050089

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