Skip to main content
SpringerLink
Log in

Alkylation of diols under phase transfer conditions: The influence of the nature of the substrate, alkylating agent, and organic solvent

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

The alkylation of ethanediol and butanediol-1,4 with allyl chloride in a two-phase system composed of an organic phase and an aqueous alkali solution was studied. It was shown that the phase transfer agent not only ensures the phase transfer effect, but also affects the reactivity of the diols. Butanediol-1,4 was alkylated with various alkylating agents. An optimal solvent for O-alkylation under the phase transfer catalysis conditions was found.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Rabinovitz, Angew. Chem. 98, 958 (1996).

    Article  Google Scholar 

  2. N. V. Morozova, N. N. Lebedeva, and L. P. Panicheva, and S. A. Panichev, Vestn. Tyumen. Gos. Univ., No. 1, 115 (2005).

  3. Properties of Organic Compounds: A Handbook, Ed. by A. A. Potekhin (Khimiya, Moscow, 1984) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Tyumen State University, Tyumen, Russia

    N. V. Morozova, N. N. Lebedeva & L. P. Panicheva

Authors
  1. N. V. Morozova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. N. Lebedeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. P. Panicheva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. V. Morozova.

Additional information

Original Russian Text © N.V. Morozova, N.N. Lebedeva, L.P. Panicheva, 2009, published in Neftekhimiya, 2009, Vol. 49, No. 5, pp. 401–404.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Morozova, N.V., Lebedeva, N.N. & Panicheva, L.P. Alkylation of diols under phase transfer conditions: The influence of the nature of the substrate, alkylating agent, and organic solvent. Pet. Chem. 49, 381–384 (2009). https://doi.org/10.1134/S0965544109050077

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544109050077

Keywords

Search

Navigation