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Catalytic arylation and alkylation of phenol with components of the 130–170°C fraction of pyrolysis products

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Abstract

The results of phenol aralkylation with components of the 130–170°C fraction of pyrolysis products on zeolite impregnated with orthophosphoric acid in a flow reactor are presented. The optimal conditions of p-aralkylphenol synthesis have been found. Under the optimal conditions, the yield of the desired aralkylphenol was 53.6% of the theoretical value and the selectivity was 95.5%. A p-aralkylphenolamine resin was synthesized on the basis of p-aralkylphenol and hexamethylenetetramine and was tested as an antioxidant for M-8 motor oil at high temperatures.

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Authors and Affiliations

  1. Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan

    Ch. K. Rasulov, A. G. Azizov, V. G. Mirzoev, R. K. Azimova, S. I. Abasov & S. Z. Alieva

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  1. Ch. K. Rasulov
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  2. A. G. Azizov
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  3. V. G. Mirzoev
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  4. R. K. Azimova
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  5. S. I. Abasov
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  6. S. Z. Alieva
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Correspondence to Ch. K. Rasulov.

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Original Russian Text © Ch.K. Rasulov, A.G. Azizov, V.G. Mirzoev, R.K. Azimova, S.I. Abasov, S.Z. Alieva, 2009, published in Neftekhimiya, 2009, Vol. 49, No. 5, pp. 397–400.

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Rasulov, C.K., Azizov, A.G., Mirzoev, V.G. et al. Catalytic arylation and alkylation of phenol with components of the 130–170°C fraction of pyrolysis products. Pet. Chem. 49, 377–380 (2009). https://doi.org/10.1134/S0965544109050065

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  • DOI: https://doi.org/10.1134/S0965544109050065

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