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Catalytic hydrogenation of dicyclopentadiene to dicyclopentene in the liquid phase

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Abstract

A new use for dicyclopentadiene has been proposed in the area of preparation of oxygen-containing compounds, including those with a cage structure, the key stage of which is the selective liquid-phase hydrogenation of dicyclopentadiene to dicyclopentene with hydrogen over finely divided hydrogenation catalysts based on platinum group metals. The process proceeds under mild conditions at atmospheric pressure. Conditions providing a yield of 92% for the desired product with an almost complete conversion of the reactant dicyclopentadiene have been determined in the study of the hydrogenation reaction in both a volumetric device of the closed type and a continuous-flow system.

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Authors and Affiliations

  1. Yaroslavl State Technical University, Moskovskii pr. 88, Yaroslavl, 150023, Russia

    T. N. Antonova, I. A. Abramov, V. Sh. Feldblyum, I. G. Abramov & A. S. Danilova

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  1. T. N. Antonova
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  2. I. A. Abramov
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  3. V. Sh. Feldblyum
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  4. I. G. Abramov
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  5. A. S. Danilova
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Corresponding author

Correspondence to T. N. Antonova.

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Original Russian Text © T.N. Antonova, I.A. Abramov, V.Sh. Feldblyum, I.G. Abramov, A.S. Danilova, 2009, published in Neftekhimiya, 2009, Vol. 49, No. 5, pp. 386–388.

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Antonova, T.N., Abramov, I.A., Feldblyum, V.S. et al. Catalytic hydrogenation of dicyclopentadiene to dicyclopentene in the liquid phase. Pet. Chem. 49, 366–368 (2009). https://doi.org/10.1134/S0965544109050041

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  • DOI: https://doi.org/10.1134/S0965544109050041

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