Abstract
The process of liquid-phase hydrogenation of the phenylacetylene byproduct in the industrial styrene fractions formed in different styrene manufacture stages at OAO Salavatnefteorgsintez was studied on specimens of the palladium-containing G-58E, APKGS-20E2, and KSVK catalysts. It was found that the KVSK catalyst, which is a silica glass-fiber matrix containing 0.2 wt % of dispersed palladium, was the most effective in the selective hydrogenation at atmospheric pressure and temperatures of 20–30°C of phenylacetylene present in the industrial fractions of styrene. It was shown that the minimal loss of styrene is attained in the case of phenylacetylene hydrogenation in the hydrocarbon condensate fraction.
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Original Russian Text © R.A. Basimova, M.L. Pavlov, S.I. Myachin, A.V. Prokopenko, A.V. Askarova, B.I. Kutepov, S.A. Sychkova, 2009, published in Neftekhimiya, 2009, Vol. 49, No. 5, pp. 380–385.
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Basimova, R.A., Pavlov, M.L., Myachin, S.I. et al. Selective hydrogenation on palladium-containing catalysts of byproduct phenylacetylene present in industrial fractions of styrene. Pet. Chem. 49, 360–365 (2009). https://doi.org/10.1134/S096554410905003X
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DOI: https://doi.org/10.1134/S096554410905003X