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Specifics of cumene oxidation in the presence of a binary mixture of initiators

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Abstract

The antagonistic effect of binary mixtures of initiators in the radical chain oxidation of hydrocarbons was experimentally revealed. The kinetics of this process was analyzed by mathematical simulation. It was shown that the antagonistic effect of the initiator mixture can be due to the cross recombination of the initiator radicals.

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References

  1. I. O. Opeida, Yu. I. Skichko, N. M. Zalevs’ka, et al., Dopov. Akad. Nauk Ukr. No. 2, 133 (2006).

  2. N. M. Emanuel, E. T. Denisov, and Z. K. Maizus, Liquid-Phase Oxidation of Hydrocarbons (Nauka, Moscow, 1965; Plenum, New York, 1967).

    Google Scholar 

  3. E. T. Denisov, Rate Constants of Homolytic Liquid-Phase Reactions (Nauka, Moscow, 1971) [in Russian].

    Google Scholar 

  4. I. A. Opeida, A. N. Shendrik, V. N. Dubina, and I. O. Kachurin, in Molecular Interactions, Structure and Reactivity of Organic Compounds (Naukova Dumka, Kiev, 1989), p. 129.

    Google Scholar 

  5. Landolt-Burnstein. Numerical Data and Functional Relationships in Science and Technology. New Series. Group II: Atomic and Molecular Physics. Vol. 13. Radical Reaction Rates in Liquids. Subvol. d (Springer, Berlin, 1984), p. 12.

  6. I. A. Opeida, A. G. Matvienko, O. Z. Bakurova, and R. A. Voloshkin, Izv. Akad. Nauk, Ser. Khim. 52(4), 1 (2003).

    Google Scholar 

  7. R. Houwink and A. J. Staverman, Chemie und Technologie der Kunststoffe (Akademische Verlagsgesellschaft, Leipzig, 1962; Khimiya, Moscow-Leningrad, 1965).

    Google Scholar 

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Authors and Affiliations

  1. Litvinenko Institute of Physicoorganic and Coal Chemistry, National Academy of Sciences of Ukraine, Donetsk, 83114, Ukraine

    I. A. Opeida, N. M. Zalevskaya, Yu. I. Skichko & R. A. Voloshkin

Authors
  1. I. A. Opeida
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  2. N. M. Zalevskaya
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  3. Yu. I. Skichko
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  4. R. A. Voloshkin
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Corresponding author

Correspondence to I. A. Opeida.

Additional information

Original Russian Text © I.A. Opeida, N.M. Zalevskaya, Yu.I. Skichko, R.A. Voloshkin, 2008, published in Neftekhimiya, 2008, Vol. 48, No. 5, pp. 378–385.

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Opeida, I.A., Zalevskaya, N.M., Skichko, Y.I. et al. Specifics of cumene oxidation in the presence of a binary mixture of initiators. Pet. Chem. 48, 381–388 (2008). https://doi.org/10.1134/S0965544108050083

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  • DOI: https://doi.org/10.1134/S0965544108050083

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