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Heterogeneous catalysis in ionic liquids: The heck reaction of bromobenzene with styrene over palladium supported on mesoporous carbon

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Abstract

Tributylhexylammonium bistriflamide [(C4H9)(C6H13)N][(CF3SO2)2N], an ionic liquid, was used as a solvent for the Heck reaction of bromobenzene with styrene in the presence of Pd deposited onto a mesoporous carbon support. It was found that dibutylamine used as a basic reagent to scavenge hydrogen bromide results in higher conversions of the reactants and higher yields of stilbene than sodium acetate. It was shown that the IL is fully recoverable after use in the catalytic reaction.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    L. A. Aslanov, V. N. Zakharov, B. V. Romanovskii & A. V. Yatsenko

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    P. M. Valetskii, Yu. A. Kabachii & S. Yu. Kochev

Authors
  1. L. A. Aslanov
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  2. P. M. Valetskii
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  3. V. N. Zakharov
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  4. Yu. A. Kabachii
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  5. S. Yu. Kochev
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  6. B. V. Romanovskii
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  7. A. V. Yatsenko
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Corresponding author

Correspondence to B. V. Romanovskii.

Additional information

Original Russian Text © L.A. Aslanov, P.M. Valetskii, V.N. Zakharov, Yu.A. Kabachii, S.Yu. Kochev, B.V. Romanovskii, A.V. Yatsenko, 2008, published in Neftekhimiya, 2008, Vol. 48, No. 5, pp. 357–362.

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Aslanov, L.A., Valetskii, P.M., Zakharov, V.N. et al. Heterogeneous catalysis in ionic liquids: The heck reaction of bromobenzene with styrene over palladium supported on mesoporous carbon. Pet. Chem. 48, 360–365 (2008). https://doi.org/10.1134/S0965544108050058

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  • DOI: https://doi.org/10.1134/S0965544108050058

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